Yttrate metathesis: Ligand design for the controlled synthesis of f-block heterobimetallic compounds

Michael S. Hill; Peter B. Hitchcock

doi:10.1002/1521-3773(20011105)40:21<4089::AID-ANIE4089>3.0.CO;2-O

Yttrate metathesis: Ligand design for the controlled synthesis of f-block heterobimetallic compounds

Michael S. Hill, Peter B. Hitchcock

University of Sussex

Research output: Contribution to journal › Article › peer-review

18 Citations (SciVal)

Abstract

The use of a Me₂Si-bridged amido-cyclopentadienyl ligand containing pendant pyridine functionality allows clean "yttrate metathesis" to occur and the synthesis of the unusual C₂-symmetric Y/Cu bimetallic compound 1.

Original language	English
Pages (from-to)	4089-4092
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	40
Issue number	21
DOIs	https://doi.org/10.1002/1521-3773(20011105)40:21<4089::AID-ANIE4089>3.0.CO;2-O
Publication status	Published - 5 Nov 2001

Keywords

Copper
Cyclopentadienyl ligands
Metathesis
N ligands
Yttrium

ASJC Scopus subject areas

Catalysis
General Chemistry

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10.1002/1521-3773(20011105)40:21<4089::AID-ANIE4089>3.0.CO;2-O

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abstract = "The use of a Me2Si-bridged amido-cyclopentadienyl ligand containing pendant pyridine functionality allows clean {"}yttrate metathesis{"} to occur and the synthesis of the unusual C2-symmetric Y/Cu bimetallic compound 1.",

keywords = "Copper, Cyclopentadienyl ligands, Metathesis, N ligands, Yttrium",

author = "Hill, {Michael S.} and Hitchcock, {Peter B.}",

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AU - Hitchcock, Peter B.

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Y1 - 2001/11/5

N2 - The use of a Me2Si-bridged amido-cyclopentadienyl ligand containing pendant pyridine functionality allows clean "yttrate metathesis" to occur and the synthesis of the unusual C2-symmetric Y/Cu bimetallic compound 1.

AB - The use of a Me2Si-bridged amido-cyclopentadienyl ligand containing pendant pyridine functionality allows clean "yttrate metathesis" to occur and the synthesis of the unusual C2-symmetric Y/Cu bimetallic compound 1.

KW - Copper

KW - Cyclopentadienyl ligands

KW - Metathesis

KW - N ligands

KW - Yttrium

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Yttrate metathesis: Ligand design for the controlled synthesis of f-block heterobimetallic compounds

Abstract

Keywords

ASJC Scopus subject areas

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