TY - JOUR
T1 - X-ray structure of HSeO 3 SnMe 2 Cl
AU - Diallo, W
AU - Diop, L
AU - Molloy, Kieran C
AU - Kociok-Kohn, Gabriele
PY - 2011/12
Y1 - 2011/12
N2 - When H 2 SeO 3 is allowed to react with SnMe 2 Cl 2 in EtOH at a 1:2 ratio colorless crystals of HSeO 3 SnMe 2 Cl are obtained which have been characterized by X-ray crystallography. The compound crystallizes in triclinic space group P1 with cell parameters a = 6.9693(5) Å, b = 7.5096(4) Å, c = 7.5222(5) Å, α = 71.503(4)°, β = 75.826(3)°, γ = 87.114(4)°, Z = 2, V = 361.82(4) Å 3 . The structure consists of [Me 3 SnO 3 SeH] n chains in which Me 3 Sn units are bridged by the selenite ligand; chains are further linked into sheets by O-H-Cl bonds. The key role of hydrogen bonds is worth emphasizing.
AB - When H 2 SeO 3 is allowed to react with SnMe 2 Cl 2 in EtOH at a 1:2 ratio colorless crystals of HSeO 3 SnMe 2 Cl are obtained which have been characterized by X-ray crystallography. The compound crystallizes in triclinic space group P1 with cell parameters a = 6.9693(5) Å, b = 7.5096(4) Å, c = 7.5222(5) Å, α = 71.503(4)°, β = 75.826(3)°, γ = 87.114(4)°, Z = 2, V = 361.82(4) Å 3 . The structure consists of [Me 3 SnO 3 SeH] n chains in which Me 3 Sn units are bridged by the selenite ligand; chains are further linked into sheets by O-H-Cl bonds. The key role of hydrogen bonds is worth emphasizing.
UR - http://www.scopus.com/inward/record.url?scp=84856149445&partnerID=8YFLogxK
UR - http://dx.doi.org/10.1515/mgmc.2011.013
U2 - 10.1515/mgmc.2011.013
DO - 10.1515/mgmc.2011.013
M3 - Article
SN - 0334-7575
VL - 34
SP - 55
EP - 56
JO - Main Group Metal Chemistry
JF - Main Group Metal Chemistry
IS - 3-4
ER -