X-ray crystal structures of [(Cy2NH2)]3 [C6H3(CO3)]_4H2O and [i-Bu2NH2][(Me3 SnO2C)2C6H3CO2]

D. Ndoye, L. Diop, K.C. Molloy, Gabriele Kociok-Kohn

Research output: Contribution to journalArticle

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Abstract

Two new benzene tricarboxylato derivatives [(CyNH )][CH(CO) ].HO (1) and [i-BuNH ][(MeSnOC) CH CO] (2) have been synthesized and characterized by X-ray crystallography. In the solid state, compound 1 shows a three dimensional structure involving intra and intermolecular hydrogen bonds, whereas the X-ray structure of 2 consists of pentacoordinated Sn centers bonded to three methyl groups and two O atoms in a trans OSnC environment, bridged by oxyanions leading to a layered structure; the cation is involved in intramolecular hydrogen bonds.
Original languageEnglish
Pages (from-to)215-219
Number of pages5
JournalMain Group Metal Chemistry
Volume36
Issue number5-6
Early online date23 Nov 2013
DOIs
Publication statusPublished - Nov 2013

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