X-ray crystal structure of the pentagonal bipyramidal nickel(II) complex [NiII(L)(H2O)2] (BF4)2 and the selective stabilisation of the nickel(I) oxidation state by a quinquedentate macrocyclic ligand

Christopher W.G. Ansell; Jack Lewis; Paul R. Raithby; John N. Ramsden; Martin Schröder

doi:10.1039/C39820000546

X-ray crystal structure of the pentagonal bipyramidal nickel(II) complex [Ni^II(L)(H₂O)₂] (BF₄)₂ and the selective stabilisation of the nickel(I) oxidation state by a quinquedentate macrocyclic ligand

Christopher W.G. Ansell, Jack Lewis, Paul R. Raithby, John N. Ramsden, Martin Schröder

University of Cambridge

Research output: Contribution to journal › Article › peer-review

Abstract

The single crystal X-ray structure of the pentagonal bipyramidal nickel (II) complex [Ni^II(L)(H₂0)₂](BF ₄)₂ involving the quinquedentate macrocyclic ligand L is reported; electrochemical reduction of a series of related nickel(II) complexes [Ni^II(L)X₂] (BF₄)₂ yields in solution d⁹ nickel (I) species.

Original language	English
Pages (from-to)	546-547
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	10
DOIs	https://doi.org/10.1039/C39820000546
Publication status	Published - 1982

ASJC Scopus subject areas

Molecular Medicine

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10.1039/C39820000546

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Ansell, C. W. G., Lewis, J., Raithby, P. R., Ramsden, J. N., & Schröder, M. (1982). X-ray crystal structure of the pentagonal bipyramidal nickel(II) complex [Ni^II(L)(H₂O)₂] (BF₄)₂ and the selective stabilisation of the nickel(I) oxidation state by a quinquedentate macrocyclic ligand. Journal of the Chemical Society, Chemical Communications, (10), 546-547. https://doi.org/10.1039/C39820000546

X-ray crystal structure of the pentagonal bipyramidal nickel(II) complex [Ni^II(L)(H₂O)₂] (BF₄)₂ and the selective stabilisation of the nickel(I) oxidation state by a quinquedentate macrocyclic ligand. / Ansell, Christopher W.G.; Lewis, Jack; Raithby, Paul R. et al.
In: Journal of the Chemical Society, Chemical Communications, No. 10, 1982, p. 546-547.

Research output: Contribution to journal › Article › peer-review

Ansell, CWG, Lewis, J, Raithby, PR, Ramsden, JN & Schröder, M 1982, 'X-ray crystal structure of the pentagonal bipyramidal nickel(II) complex [Ni^II(L)(H₂O)₂] (BF₄)₂ and the selective stabilisation of the nickel(I) oxidation state by a quinquedentate macrocyclic ligand', Journal of the Chemical Society, Chemical Communications, no. 10, pp. 546-547. https://doi.org/10.1039/C39820000546

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abstract = "The single crystal X-ray structure of the pentagonal bipyramidal nickel (II) complex [NiII(L)(H20)2](BF 4)2 involving the quinquedentate macrocyclic ligand L is reported; electrochemical reduction of a series of related nickel(II) complexes [NiII(L)X2] (BF4)2 yields in solution d9 nickel (I) species.",

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AU - Raithby, Paul R.

AU - Ramsden, John N.

AU - Schröder, Martin

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AB - The single crystal X-ray structure of the pentagonal bipyramidal nickel (II) complex [NiII(L)(H20)2](BF 4)2 involving the quinquedentate macrocyclic ligand L is reported; electrochemical reduction of a series of related nickel(II) complexes [NiII(L)X2] (BF4)2 yields in solution d9 nickel (I) species.

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DO - 10.1039/C39820000546

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X-ray crystal structure of the pentagonal bipyramidal nickel(II) complex [Ni^II(L)(H₂O)₂] (BF₄)₂ and the selective stabilisation of the nickel(I) oxidation state by a quinquedentate macrocyclic ligand

Abstract

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