Wurtz synthesis of high molecular weight poly(dibutylstannane)

Nathalie Devylder; Michael Hill; Kieran C. Molloy; Gareth J. Price

doi:10.1039/cc9960000711

Wurtz synthesis of high molecular weight poly(dibutylstannane)

Nathalie Devylder
, Michael Hill
, Kieran C. Molloy
, Gareth J. Price

University of Bath

Research output: Contribution to journal › Article › peer-review

54 Citations (SciVal)

Abstract

Dibutyltin polymers with much higher molecular weights (GPC, polystyrene standards: M_n = ca. 1 × 10⁶) than previously reported are prepared by Wurtz coupling of Bu₂SnCl₂ monomer; the reaction conditions are critical in achieving the maximum chain length, as polymer degradation results from prolonged reaction times.

Original language	English
Pages (from-to)	711-712
Number of pages	2
Journal	Chemical Communications
Issue number	6
DOIs	https://doi.org/10.1039/cc9960000711
Publication status	Published - 1996

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/cc9960000711

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title = "Wurtz synthesis of high molecular weight poly(dibutylstannane)",

abstract = "Dibutyltin polymers with much higher molecular weights (GPC, polystyrene standards: Mn = ca. 1 × 106) than previously reported are prepared by Wurtz coupling of Bu2SnCl2 monomer; the reaction conditions are critical in achieving the maximum chain length, as polymer degradation results from prolonged reaction times.",

author = "Nathalie Devylder and Michael Hill and Molloy, \{Kieran C.\} and Price, \{Gareth J.\}",

year = "1996",

doi = "10.1039/cc9960000711",

language = "English",

pages = "711--712",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

number = "6",

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T1 - Wurtz synthesis of high molecular weight poly(dibutylstannane)

AU - Devylder, Nathalie

AU - Hill, Michael

AU - Molloy, Kieran C.

AU - Price, Gareth J.

PY - 1996

Y1 - 1996

N2 - Dibutyltin polymers with much higher molecular weights (GPC, polystyrene standards: Mn = ca. 1 × 106) than previously reported are prepared by Wurtz coupling of Bu2SnCl2 monomer; the reaction conditions are critical in achieving the maximum chain length, as polymer degradation results from prolonged reaction times.

AB - Dibutyltin polymers with much higher molecular weights (GPC, polystyrene standards: Mn = ca. 1 × 106) than previously reported are prepared by Wurtz coupling of Bu2SnCl2 monomer; the reaction conditions are critical in achieving the maximum chain length, as polymer degradation results from prolonged reaction times.

UR - https://www.scopus.com/pages/publications/0002642262

U2 - 10.1039/cc9960000711

DO - 10.1039/cc9960000711

M3 - Article

AN - SCOPUS:0002642262

SN - 1359-7345

SP - 711

EP - 712

JO - Chemical Communications

JF - Chemical Communications

IS - 6

ER -

Wurtz synthesis of high molecular weight poly(dibutylstannane)

Abstract

ASJC Scopus subject areas

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