Wurtz synthesis of high molecular weight poly(dibutylstannane)

Nathalie Devylder; Michael Hill; Kieran C. Molloy; Gareth J. Price

doi:10.1039/cc9960000711

Wurtz synthesis of high molecular weight poly(dibutylstannane)

Nathalie Devylder, Michael Hill, Kieran C. Molloy, Gareth J. Price

University of Bath

Research output: Contribution to journal › Article › peer-review

48 Citations (SciVal)

Abstract

Dibutyltin polymers with much higher molecular weights (GPC, polystyrene standards: M_n = ca. 1 × 10⁶) than previously reported are prepared by Wurtz coupling of Bu₂SnCl₂ monomer; the reaction conditions are critical in achieving the maximum chain length, as polymer degradation results from prolonged reaction times.

Original language	English
Pages (from-to)	711-712
Number of pages	2
Journal	Chemical Communications
Issue number	6
DOIs	https://doi.org/10.1039/cc9960000711
Publication status	Published - 1996

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Access to Document

10.1039/cc9960000711

Cite this

@article{5d45ee3e782d486194b65e8b33d901ec,

title = "Wurtz synthesis of high molecular weight poly(dibutylstannane)",

abstract = "Dibutyltin polymers with much higher molecular weights (GPC, polystyrene standards: Mn = ca. 1 × 106) than previously reported are prepared by Wurtz coupling of Bu2SnCl2 monomer; the reaction conditions are critical in achieving the maximum chain length, as polymer degradation results from prolonged reaction times.",

author = "Nathalie Devylder and Michael Hill and Molloy, {Kieran C.} and Price, {Gareth J.}",

year = "1996",

doi = "10.1039/cc9960000711",

language = "English",

pages = "711--712",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "6",

}

TY - JOUR

T1 - Wurtz synthesis of high molecular weight poly(dibutylstannane)

AU - Devylder, Nathalie

AU - Hill, Michael

AU - Molloy, Kieran C.

AU - Price, Gareth J.

PY - 1996

Y1 - 1996

N2 - Dibutyltin polymers with much higher molecular weights (GPC, polystyrene standards: Mn = ca. 1 × 106) than previously reported are prepared by Wurtz coupling of Bu2SnCl2 monomer; the reaction conditions are critical in achieving the maximum chain length, as polymer degradation results from prolonged reaction times.

AB - Dibutyltin polymers with much higher molecular weights (GPC, polystyrene standards: Mn = ca. 1 × 106) than previously reported are prepared by Wurtz coupling of Bu2SnCl2 monomer; the reaction conditions are critical in achieving the maximum chain length, as polymer degradation results from prolonged reaction times.

UR - http://www.scopus.com/inward/record.url?scp=0002642262&partnerID=8YFLogxK

U2 - 10.1039/cc9960000711

DO - 10.1039/cc9960000711

M3 - Article

AN - SCOPUS:0002642262

SN - 1359-7345

SP - 711

EP - 712

JO - Chemical Communications

JF - Chemical Communications

IS - 6

ER -

Wurtz synthesis of high molecular weight poly(dibutylstannane)

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this