Well-defined indium(III) N-heterocyclic carbene complexes with triflate ligands: Structural models for the In(OTf)3 catalyst

J.H. Cotgreave; D. Colclough; Gabriele Kociok-Kohn; G. Ruggiero; C.G. Frost; A.S. Weller

doi:10.1039/B404179H

Well-defined indium(III) N-heterocyclic carbene complexes with triflate ligands: Structural models for the In(OTf)₃ catalyst

J.H. Cotgreave, D. Colclough, Gabriele Kociok-Kohn, G. Ruggiero, C.G. Frost, A.S. Weller

GlaxoSmithKline

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18 Citations (SciVal)

Abstract

Reaction of 1,3-dimesitylimidazolium chloride [IMesH]Cl with InMe₃ results in (IMes)InMe₂Cl, which on treatment with one equivalent of TMS-OTf affords (IMes)InMe₂(OTf), which can be converted to the bistriflate complex (IMes)In(Me)(OTf)₂ on addition of HOTf.

Original language	English
Pages (from-to)	1519-1520
Number of pages	2
Journal	Dalton Transactions
Volume	2004
Issue number	10
DOIs	https://doi.org/10.1039/B404179H
Publication status	Published - 21 May 2004

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title = "Well-defined indium(III) N-heterocyclic carbene complexes with triflate ligands: Structural models for the In(OTf)3 catalyst",

abstract = "Reaction of 1,3-dimesitylimidazolium chloride [IMesH]Cl with InMe3 results in (IMes)InMe2Cl, which on treatment with one equivalent of TMS-OTf affords (IMes)InMe2(OTf), which can be converted to the bistriflate complex (IMes)In(Me)(OTf)2 on addition of HOTf.",

author = "J.H. Cotgreave and D. Colclough and Gabriele Kociok-Kohn and G. Ruggiero and C.G. Frost and A.S. Weller",

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T1 - Well-defined indium(III) N-heterocyclic carbene complexes with triflate ligands

T2 - Structural models for the In(OTf)3 catalyst

AU - Cotgreave, J.H.

AU - Colclough, D.

AU - Kociok-Kohn, Gabriele

AU - Ruggiero, G.

AU - Frost, C.G.

AU - Weller, A.S.

PY - 2004/5/21

Y1 - 2004/5/21

N2 - Reaction of 1,3-dimesitylimidazolium chloride [IMesH]Cl with InMe3 results in (IMes)InMe2Cl, which on treatment with one equivalent of TMS-OTf affords (IMes)InMe2(OTf), which can be converted to the bistriflate complex (IMes)In(Me)(OTf)2 on addition of HOTf.

AB - Reaction of 1,3-dimesitylimidazolium chloride [IMesH]Cl with InMe3 results in (IMes)InMe2Cl, which on treatment with one equivalent of TMS-OTf affords (IMes)InMe2(OTf), which can be converted to the bistriflate complex (IMes)In(Me)(OTf)2 on addition of HOTf.

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UR - http://dx.doi.org/10.1039/B404179H

U2 - 10.1039/B404179H

DO - 10.1039/B404179H

M3 - Article

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SN - 1477-9226

VL - 2004

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JO - Dalton Transactions

JF - Dalton Transactions

IS - 10

ER -

Well-defined indium(III) N-heterocyclic carbene complexes with triflate ligands: Structural models for the In(OTf)₃ catalyst

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