Well-defined indium(III) N-heterocyclic carbene complexes with triflate ligands

Structural models for the In(OTf)3 catalyst

J.H. Cotgreave, D. Colclough, Gabriele Kociok-Kohn, G. Ruggiero, C.G. Frost, A.S. Weller

Research output: Contribution to journalArticle

18 Citations (Scopus)

Abstract

Reaction of 1,3-dimesitylimidazolium chloride [IMesH]Cl with InMe3 results in (IMes)InMe2Cl, which on treatment with one equivalent of TMS-OTf affords (IMes)InMe2(OTf), which can be converted to the bistriflate complex (IMes)In(Me)(OTf)2 on addition of HOTf.

Original languageEnglish
Pages (from-to)1519-1520
Number of pages2
JournalDalton Transactions
Volume2004
Issue number10
DOIs
Publication statusPublished - 21 May 2004

Fingerprint

Indium
Chlorides
Ligands
Catalysts
carbene

Cite this

Well-defined indium(III) N-heterocyclic carbene complexes with triflate ligands : Structural models for the In(OTf)3 catalyst. / Cotgreave, J.H.; Colclough, D.; Kociok-Kohn, Gabriele; Ruggiero, G.; Frost, C.G.; Weller, A.S.

In: Dalton Transactions, Vol. 2004, No. 10, 21.05.2004, p. 1519-1520.

Research output: Contribution to journalArticle

@article{21afd5d8e389459dabf4925e436f085c,
title = "Well-defined indium(III) N-heterocyclic carbene complexes with triflate ligands: Structural models for the In(OTf)3 catalyst",
abstract = "Reaction of 1,3-dimesitylimidazolium chloride [IMesH]Cl with InMe3 results in (IMes)InMe2Cl, which on treatment with one equivalent of TMS-OTf affords (IMes)InMe2(OTf), which can be converted to the bistriflate complex (IMes)In(Me)(OTf)2 on addition of HOTf.",
author = "J.H. Cotgreave and D. Colclough and Gabriele Kociok-Kohn and G. Ruggiero and C.G. Frost and A.S. Weller",
year = "2004",
month = "5",
day = "21",
doi = "10.1039/B404179H",
language = "English",
volume = "2004",
pages = "1519--1520",
journal = "Dalton Transactions",
issn = "1477-9226",
publisher = "Royal Society of Chemistry",
number = "10",

}

TY - JOUR

T1 - Well-defined indium(III) N-heterocyclic carbene complexes with triflate ligands

T2 - Structural models for the In(OTf)3 catalyst

AU - Cotgreave, J.H.

AU - Colclough, D.

AU - Kociok-Kohn, Gabriele

AU - Ruggiero, G.

AU - Frost, C.G.

AU - Weller, A.S.

PY - 2004/5/21

Y1 - 2004/5/21

N2 - Reaction of 1,3-dimesitylimidazolium chloride [IMesH]Cl with InMe3 results in (IMes)InMe2Cl, which on treatment with one equivalent of TMS-OTf affords (IMes)InMe2(OTf), which can be converted to the bistriflate complex (IMes)In(Me)(OTf)2 on addition of HOTf.

AB - Reaction of 1,3-dimesitylimidazolium chloride [IMesH]Cl with InMe3 results in (IMes)InMe2Cl, which on treatment with one equivalent of TMS-OTf affords (IMes)InMe2(OTf), which can be converted to the bistriflate complex (IMes)In(Me)(OTf)2 on addition of HOTf.

UR - http://www.scopus.com/inward/record.url?scp=3042724759&partnerID=8YFLogxK

UR - http://dx.doi.org/10.1039/B404179H

U2 - 10.1039/B404179H

DO - 10.1039/B404179H

M3 - Article

VL - 2004

SP - 1519

EP - 1520

JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9226

IS - 10

ER -