Abstract
A theoretical investigation of weak-anchoring effects in a thin two-dimensional pinned static ridge of nematic liquid crystal resting on a flat solid substrate in an atmosphere of passive gas is performed. Specifically, we solve a reduced version of the general system of governing equations recently derived by Cousins et al. [Proc. R. Soc. A 478, 20210849 (2022)] valid for a symmetric thin ridge under the one-constant approximation of the Frank-Oseen bulk elastic energy with pinned contact lines to determine the shape of the ridge and the behavior of the director within it. Numerical investigations covering a wide range of parameter values indicate that the energetically preferred solutions can be classified in terms of the Jenkins-Barratt-Barbero-Barberi critical thickness into five qualitatively different types of solution. In particular, the theoretical results suggest that anchoring breaking occurs close to the contact lines. The theoretical predictions are supported by the results of physical experiments for a ridge of the nematic 4′-pentyl-4-biphenylcarbonitrile (5CB). In particular, these experiments show that the homeotropic anchoring at the gas-nematic interface is broken close to the contact lines by the stronger rubbed planar anchoring at the nematic-substrate interface. A comparison between the experimental values of and the theoretical predictions for the effective refractive index of the ridge gives a first estimate of the anchoring strength of an interface between air and 5CB to be (9.80±1.12)×10−6Nm−1 at a temperature of (22±1.5)∘C.
Original language | English |
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Article number | 034702 |
Journal | Physical Review E |
Volume | 107 |
Issue number | 3 |
Early online date | 16 Mar 2023 |
DOIs | |
Publication status | Published - 16 Mar 2023 |
Data Availability Statement
The theoretical data used to produce Figs. 4–6 may be generated using the numerical procedure for solving the system Eqs. (15)–(17) and Eqs. (27)–(29) described in Appendix A. The experimental data that support the findings of this study are available upon request from Professor Carl Brown [73]at Nottingham Trent University.Funding
The theoretical work was supported by United Kingdom Engineering and Physical Sciences Research Council (EPSRC) research grants EP/P51066X/1 and EP/T012501/2, the University of Strathclyde, the University of Glasgow, and Merck KGaA. The experimental work, which was carried out at Nottingham Trent University, was supported by EPSRC research grant EP/T012986/1.