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Vertical stratification and metabolic versatility of methanogens in Haima cold seep sediments: Alkane-fueled acetoclastic methanogenesis revealed by metagenomics and experimental verification

  • Lijia Jiang
  • , Zhengjiao Liang
  • , Tom Williams
  • , Yinan Deng
  • , Hao Yu
  • , Qian Hao
  • , Jun Cao
  • , Hanghai Zhou
  • , Hongfei Lai
  • , Jiawang Chen
  • , Haixin Chen
  • , Chunfang Zhang
  • Zhejiang University
  • BGI Research
  • Guangzhou Marine Geological Survey
  • Zhejiang Academy of Agricultural Sciences

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Abstract

Cold seeps are hot spots for studying the biogeochemical processes mediated by methyl-coenzyme M reductase (MCR) containing archaea, yet these processes remain poorly understood. Here, we investigated the microbial communities in a 5-m-long sediment core encompassing sulfate-methane transition zone (SMTZ), collected from the Haima cold seep. We focused on distinct biogeochemical characteristics and metagenomics to study the vertical patterns of mcrA-containing archaea and their role in alkane metabolism. Background alkane analysis showed that long chain alkanes were dominant in the sediment core. Metagenomic and quantitative PCR (qPCR) analysis revealed that the abundance of mcrA gene within and below the SMTZ were substantially higher than those above the SMTZ. We recovered 21 mcrA-containing MAGs, 11 affiliated with Methanosarcinaceae. One MAG (CG1-BIN56) encoded complete key genes for all three methanogenic pathways. Functional gene profiles suggested that acetoclastic methanogenesis is the dominant pathway. Furthermore, a 10-month anaerobic enrichment with n-alkanes (C10/C16) using SMTZ (CG15: 350 cmbsf) inocula exhibited high degradation rate (C10: 94.2% ± 2.5%, C16: 66.8% ± 2.8%) accompanied by acetate accumulation. These findings suggest that acetate, as a likely intermediate associated with alkane degradation process, potentially fuels acetoclastic methanogenesis. This indicates a likely syntrophic interaction between alkane-degrading and methane-cycling microorganisms in cold seep sediments.
Original languageEnglish
Article number107972
Number of pages12
JournalMarine Environmental Research
Volume217
Early online date13 Mar 2026
DOIs
Publication statusPublished - 1 May 2026

Data Availability Statement

Raw sequences were deposited in the Sequence Read Archive database at NCBI with the accession number PRJNA1254324.

Acknowledgements

We are very grateful for the support provided by the HPC Center of ZJU (ZHOUSHAN CAMPUS) and the High-performance Computing Platform of YZBSTCACC.

Funding

This study was financially supported by the Guangdong Major Project of Basic and Applied Basic Research (2023B0303000015), the Project of Sanya Yazhou Bay Science and Technology City (Grant No: SKJC-2024-01-002), the National Natural Science Foundation of China (No. 42406135), the National Engineering Research Center of Gas Hydrate Exploration and Development Project (No. NERC2024001) and the Guangdong Basic and Applied Basic Research (No. 2023A1515010913, 2022A1515110569).We are very grateful for the support provided by the HPC Center of ZJU (ZHOUSHAN CAMPUS) and the High-performance Computing Platform of YZBSTCACC. This study was financially supported by the Guangdong Major Project of Basic and Applied Basic Research ( 2023B0303000015 ), the Project of Sanya Yazhou Bay Science and Technology City (Grant No: SKJC-2024-01-002 ), the National Natural Science Foundation of China (No. 42406135 ), the National Engineering Research Center of Gas Hydrate Exploration and Development Project (No. NERC2024001 ) and the Guangdong Basic and Applied Basic Research (No. 2023A1515010913, 2022A1515110569 ).

FundersFunder number
Cao Guangbiao High Science and Technology Foundation, Zhejiang University
National Engineering Research Center of Gas Hydrate Exploration and Development ProjectNERC2024001
National Natural Science Foundation of China42406135
Guangdong Major Project of Basic and Applied Basic Research2023B0303000015
Basic and Applied Basic Research Foundation of Guangdong Province2023A1515010913, 2022A1515110569
Sanya Yazhou Bay Science and Technology CitySKJC-2024-01-002

    Keywords

    • cold seep sediments
    • Biogeochemical integration
    • Acetoclastic methanogens
    • Alkanes metabolism
    • Syntrophic interaction

    ASJC Scopus subject areas

    • Oceanography
    • Aquatic Science
    • Pollution

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