Use of trimethylamine N-oxide in the controlled air-oxidation of metal carbonyl complexes; synthesis and crystal structure of a novel organometallic oxo complex of dimolybdenum

Joanne C. Stichbury; Martin J. Mays; Paul R. Raithby; Moira Ann Rennie; Michael R. Fullalove

doi:10.1039/C39950001269

Use of trimethylamine N-oxide in the controlled air-oxidation of metal carbonyl complexes; synthesis and crystal structure of a novel organometallic oxo complex of dimolybdenum

Joanne C. Stichbury, Martin J. Mays, Paul R. Raithby, Moira Ann Rennie, Michael R. Fullalove

University of Cambridge

Research output: Contribution to journal › Article › peer-review

Abstract

The air oxidation of [Mo₂(CO)₄(μ-RCCR′) (η⁵-C₅H₅)₂] in the presence of trimethylamine N-oxide affords the novel organometallic complexes [Mo ₂O₂(μ-O)(μ-RCCR′)(η⁵-C ₅H₅)₂] (R=R′=CO₂Me or Ph; R=CO₂Me, R′=H; R=Ph, R′=H) which are characterised spectroscopically; the structure of [Mo₂O₂(μ-O)(μ- MeO₂C-C₂-CO₂Me)(η⁵-C ₅H₅)₂] 1 is determined by X-ray crystallography.

Original language	English
Pages (from-to)	1269-1270
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	12
DOIs	https://doi.org/10.1039/C39950001269
Publication status	Published - 31 Dec 1995

ASJC Scopus subject areas

Molecular Medicine

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Stichbury, J. C., Mays, M. J., Raithby, P. R., Rennie, M. A., & Fullalove, M. R. (1995). Use of trimethylamine N-oxide in the controlled air-oxidation of metal carbonyl complexes; synthesis and crystal structure of a novel organometallic oxo complex of dimolybdenum. Journal of the Chemical Society, Chemical Communications, (12), 1269-1270. https://doi.org/10.1039/C39950001269

Use of trimethylamine N-oxide in the controlled air-oxidation of metal carbonyl complexes; synthesis and crystal structure of a novel organometallic oxo complex of dimolybdenum. / Stichbury, Joanne C.; Mays, Martin J.; Raithby, Paul R. et al.
In: Journal of the Chemical Society, Chemical Communications, No. 12, 31.12.1995, p. 1269-1270.

Research output: Contribution to journal › Article › peer-review

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title = "Use of trimethylamine N-oxide in the controlled air-oxidation of metal carbonyl complexes; synthesis and crystal structure of a novel organometallic oxo complex of dimolybdenum",

abstract = "The air oxidation of [Mo2(CO)4(μ-RCCR′) (η5-C5H5)2] in the presence of trimethylamine N-oxide affords the novel organometallic complexes [Mo 2O2(μ-O)(μ-RCCR′)(η5-C 5H5)2] (R=R′=CO2Me or Ph; R=CO2Me, R′=H; R=Ph, R′=H) which are characterised spectroscopically; the structure of [Mo2O2(μ-O)(μ- MeO2C-C2-CO2Me)(η5-C 5H5)2] 1 is determined by X-ray crystallography.",

author = "Stichbury, \{Joanne C.\} and Mays, \{Martin J.\} and Raithby, \{Paul R.\} and Rennie, \{Moira Ann\} and Fullalove, \{Michael R.\}",

year = "1995",

month = dec,

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doi = "10.1039/C39950001269",

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journal = "Journal of the Chemical Society, Chemical Communications",

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AU - Stichbury, Joanne C.

AU - Mays, Martin J.

AU - Raithby, Paul R.

AU - Rennie, Moira Ann

AU - Fullalove, Michael R.

PY - 1995/12/31

Y1 - 1995/12/31

N2 - The air oxidation of [Mo2(CO)4(μ-RCCR′) (η5-C5H5)2] in the presence of trimethylamine N-oxide affords the novel organometallic complexes [Mo 2O2(μ-O)(μ-RCCR′)(η5-C 5H5)2] (R=R′=CO2Me or Ph; R=CO2Me, R′=H; R=Ph, R′=H) which are characterised spectroscopically; the structure of [Mo2O2(μ-O)(μ- MeO2C-C2-CO2Me)(η5-C 5H5)2] 1 is determined by X-ray crystallography.

AB - The air oxidation of [Mo2(CO)4(μ-RCCR′) (η5-C5H5)2] in the presence of trimethylamine N-oxide affords the novel organometallic complexes [Mo 2O2(μ-O)(μ-RCCR′)(η5-C 5H5)2] (R=R′=CO2Me or Ph; R=CO2Me, R′=H; R=Ph, R′=H) which are characterised spectroscopically; the structure of [Mo2O2(μ-O)(μ- MeO2C-C2-CO2Me)(η5-C 5H5)2] 1 is determined by X-ray crystallography.

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IS - 12

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Use of trimethylamine N-oxide in the controlled air-oxidation of metal carbonyl complexes; synthesis and crystal structure of a novel organometallic oxo complex of dimolybdenum

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