TY - JOUR
T1 - Use of trimethylamine N-oxide in the controlled air-oxidation of metal carbonyl complexes; synthesis and crystal structure of a novel organometallic oxo complex of dimolybdenum
AU - Stichbury, Joanne C.
AU - Mays, Martin J.
AU - Raithby, Paul R.
AU - Rennie, Moira Ann
AU - Fullalove, Michael R.
PY - 1995/12/31
Y1 - 1995/12/31
N2 - The air oxidation of [Mo2(CO)4(μ-RCCR′) (η5-C5H5)2] in the presence of trimethylamine N-oxide affords the novel organometallic complexes [Mo 2O2(μ-O)(μ-RCCR′)(η5-C 5H5)2] (R=R′=CO2Me or Ph; R=CO2Me, R′=H; R=Ph, R′=H) which are characterised spectroscopically; the structure of [Mo2O2(μ-O)(μ- MeO2C-C2-CO2Me)(η5-C 5H5)2] 1 is determined by X-ray crystallography.
AB - The air oxidation of [Mo2(CO)4(μ-RCCR′) (η5-C5H5)2] in the presence of trimethylamine N-oxide affords the novel organometallic complexes [Mo 2O2(μ-O)(μ-RCCR′)(η5-C 5H5)2] (R=R′=CO2Me or Ph; R=CO2Me, R′=H; R=Ph, R′=H) which are characterised spectroscopically; the structure of [Mo2O2(μ-O)(μ- MeO2C-C2-CO2Me)(η5-C 5H5)2] 1 is determined by X-ray crystallography.
UR - http://www.scopus.com/inward/record.url?scp=37049068683&partnerID=8YFLogxK
U2 - 10.1039/C39950001269
DO - 10.1039/C39950001269
M3 - Article
AN - SCOPUS:37049068683
SN - 0022-4936
SP - 1269
EP - 1270
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 12
ER -