Use of the magnetic suspension balance for the study of polymersolutions

A. J. Ashworth; G. J. Price

doi:10.1016/0040-6031(84)87284-6

Use of the magnetic suspension balance for the study of polymersolutions

A. J. Ashworth, G. J. Price

Department of Chemistry

University of Bath

Research output: Contribution to journal › Article › peer-review

Abstract

The method involves the isothermal gravimetric determination of the absorption of an organic vapour into a thin film of liquid polymer spread upon an inert particulate support. Results are presented for the absorption of benzene and cyclohexane at 25°C in poly (dimethylsiloxane), and the concentration variation of the interaction parameter determined is compared with that found by other workers. The determination of the partial molar enthalpy of mixing was also examined by studying the absorption of hexane in poly (dimethylsiloxane) over the temperature range of 25 to 35°C, and comparing the value obtained with published values.

Original language	English
Pages (from-to)	161-170
Number of pages	10
Journal	Thermochimica Acta
Volume	82
Issue number	1
DOIs	https://doi.org/10.1016/0040-6031(84)87284-6
Publication status	Published - 1 Dec 1984

ASJC Scopus subject areas

Instrumentation
Condensed Matter Physics
Physical and Theoretical Chemistry

Access to Document

10.1016/0040-6031(84)87284-6

Cite this

@article{30cd7ee04b384720bcd0690c5f4b2d25,

title = "Use of the magnetic suspension balance for the study of polymersolutions",

abstract = "The method involves the isothermal gravimetric determination of the absorption of an organic vapour into a thin film of liquid polymer spread upon an inert particulate support. Results are presented for the absorption of benzene and cyclohexane at 25°C in poly (dimethylsiloxane), and the concentration variation of the interaction parameter determined is compared with that found by other workers. The determination of the partial molar enthalpy of mixing was also examined by studying the absorption of hexane in poly (dimethylsiloxane) over the temperature range of 25 to 35°C, and comparing the value obtained with published values.",

author = "Ashworth, {A. J.} and Price, {G. J.}",

year = "1984",

month = dec,

day = "1",

doi = "10.1016/0040-6031(84)87284-6",

language = "English",

volume = "82",

pages = "161--170",

journal = "Thermochimica Acta",

issn = "0040-6031",

publisher = "Elsevier",

number = "1",

}

TY - JOUR

T1 - Use of the magnetic suspension balance for the study of polymersolutions

AU - Ashworth, A. J.

AU - Price, G. J.

PY - 1984/12/1

Y1 - 1984/12/1

N2 - The method involves the isothermal gravimetric determination of the absorption of an organic vapour into a thin film of liquid polymer spread upon an inert particulate support. Results are presented for the absorption of benzene and cyclohexane at 25°C in poly (dimethylsiloxane), and the concentration variation of the interaction parameter determined is compared with that found by other workers. The determination of the partial molar enthalpy of mixing was also examined by studying the absorption of hexane in poly (dimethylsiloxane) over the temperature range of 25 to 35°C, and comparing the value obtained with published values.

AB - The method involves the isothermal gravimetric determination of the absorption of an organic vapour into a thin film of liquid polymer spread upon an inert particulate support. Results are presented for the absorption of benzene and cyclohexane at 25°C in poly (dimethylsiloxane), and the concentration variation of the interaction parameter determined is compared with that found by other workers. The determination of the partial molar enthalpy of mixing was also examined by studying the absorption of hexane in poly (dimethylsiloxane) over the temperature range of 25 to 35°C, and comparing the value obtained with published values.

UR - http://www.scopus.com/inward/record.url?scp=0345032186&partnerID=8YFLogxK

U2 - 10.1016/0040-6031(84)87284-6

DO - 10.1016/0040-6031(84)87284-6

M3 - Article

AN - SCOPUS:0345032186

SN - 0040-6031

VL - 82

SP - 161

EP - 170

JO - Thermochimica Acta

JF - Thermochimica Acta

IS - 1

ER -

Use of the magnetic suspension balance for the study of polymersolutions

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this