TY - JOUR
T1 - Use of [Ru(η5-C5H5)(MeCN)3]+ as a capping reagent in cluster build-up
T2 - Synthesis and structural characterisation of [Os5Ru2(CO)15(η5-C 5H5)2]
AU - Lewis, Jack
AU - Morewood, Catherine A.
AU - Raithby, Paul R.
AU - Ramirez De Arellano, M. Carmen
PY - 1996/12/21
Y1 - 1996/12/21
N2 - Ionic coupling of the mononuclear cation [Ru(η5-C5H5)-(MeCN)3] + with the cluster dianion [Os5(CO)15]2- afforded the neutral heptanuclear cluster [Os5Ru2(CO)15(η5-C 5H5)2] which has been shown by X-ray diffraction studies to contain a tricapped tetrahedral metal core.
AB - Ionic coupling of the mononuclear cation [Ru(η5-C5H5)-(MeCN)3] + with the cluster dianion [Os5(CO)15]2- afforded the neutral heptanuclear cluster [Os5Ru2(CO)15(η5-C 5H5)2] which has been shown by X-ray diffraction studies to contain a tricapped tetrahedral metal core.
UR - http://www.scopus.com/inward/record.url?scp=33748446694&partnerID=8YFLogxK
U2 - 10.1039/DT9960004509
DO - 10.1039/DT9960004509
M3 - Article
AN - SCOPUS:33748446694
SN - 0300-9246
VL - 1996
SP - 4509
EP - 4510
JO - Journal of the Chemical Society - Dalton Transactions
JF - Journal of the Chemical Society - Dalton Transactions
IS - 24
ER -