Upgrading biogenic furans: blended C10–C12 platform chemicals via lyase-catalyzed carboligations and formation of novel C12 –choline chloride-based deep-eutectic-solvents

Joseph Donnelly; C Muller; Lotte  Wiemans; Christopher Chuck; Pablo  Dominguez

doi:10.1039/C5GC00342C

Upgrading biogenic furans: blended C₁₀–C₁₂ platform chemicals via lyase-catalyzed carboligations and formation of novel C₁₂ –choline chloride-based deep-eutectic-solvents

Joseph Donnelly, C Muller, Lotte Wiemans , Christopher Chuck, Pablo Dominguez

RWTH Aachen University

Research output: Contribution to journal › Article › peer-review

31 Citations (SciVal)

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Abstract

Benzaldehyde lyase (BAL) results in an efficient biocatalyst for theumpolung carboligation of furfural, HMF, and mixtures of them,leading to blended C₁₀–C₁₂platform chemicals. Subsequently, themixing and gentle heating (<100 °C) of the formed hydroxy-ketonewith choline chloride leads to the formation of a novel biomassderiveddeep-eutectic-solvent.

Original language	English
Pages (from-to)	2714-2718
Journal	Green Chemistry
Volume	17
Issue number	5
Early online date	9 Mar 2015
DOIs	https://doi.org/10.1039/C5GC00342C
Publication status	Published - 1 May 2015

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10.1039/C5GC00342C

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abstract = "Benzaldehyde lyase (BAL) results in an efficient biocatalyst for theumpolung carboligation of furfural, HMF, and mixtures of them,leading to blended C10–C12 platform chemicals. Subsequently, themixing and gentle heating (<100 °C) of the formed hydroxy-ketonewith choline chloride leads to the formation of a novel biomassderiveddeep-eutectic-solvent.",

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AU - Muller, C

AU - Wiemans , Lotte

AU - Chuck, Christopher

AU - Dominguez , Pablo

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AB - Benzaldehyde lyase (BAL) results in an efficient biocatalyst for theumpolung carboligation of furfural, HMF, and mixtures of them,leading to blended C10–C12 platform chemicals. Subsequently, themixing and gentle heating (<100 °C) of the formed hydroxy-ketonewith choline chloride leads to the formation of a novel biomassderiveddeep-eutectic-solvent.

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Upgrading biogenic furans: blended C₁₀–C₁₂ platform chemicals via lyase-catalyzed carboligations and formation of novel C₁₂ –choline chloride-based deep-eutectic-solvents

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