Upgrading biogenic furans

blended C10–C12 platform chemicals via lyase-catalyzed carboligations and formation of novel C12 –choline chloride-based deep-eutectic-solvents

Joseph Donnelly, C Muller, Lotte Wiemans , Christopher Chuck, Pablo Dominguez

Research output: Contribution to journalArticle

16 Citations (Scopus)
84 Downloads (Pure)

Abstract

Benzaldehyde lyase (BAL) results in an efficient biocatalyst for theumpolung carboligation of furfural, HMF, and mixtures of them,leading to blended C10–C12 platform chemicals. Subsequently, themixing and gentle heating (<100 °C) of the formed hydroxy-ketonewith choline chloride leads to the formation of a novel biomassderiveddeep-eutectic-solvent.
Original languageEnglish
Pages (from-to)2714-2718
JournalGreen Chemistry
Volume17
Issue number5
Early online date9 Mar 2015
DOIs
Publication statusPublished - 1 May 2015

Fingerprint

Furaldehyde
Furans
Furfural
Biocatalysts
Lyases
furan
Choline
Eutectics
chloride
heating
Heating
Enzymes
benzaldehyde lyase
chemical

Cite this

Upgrading biogenic furans : blended C10–C12 platform chemicals via lyase-catalyzed carboligations and formation of novel C12 –choline chloride-based deep-eutectic-solvents. / Donnelly, Joseph; Muller, C; Wiemans , Lotte ; Chuck, Christopher; Dominguez , Pablo .

In: Green Chemistry, Vol. 17, No. 5, 01.05.2015, p. 2714-2718.

Research output: Contribution to journalArticle

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