Unsymmetrically-substituted 2,4,6-trimercaptotriazine: supramolecular self-assembly through C=S center dot center dot center dot H-N hydrogen bonds in the crystal structures of C3N3S3H2Na center dot 3H(2)O and C3N3S3H2Cu(PPh3)(2)

M F Mahon; K C Molloy; M M Venter; L Haiduc

doi:10.1016/s0020-1693(02)01468-8

Unsymmetrically-substituted 2,4,6-trimercaptotriazine: supramolecular self-assembly through C=S center dot center dot center dot H-N hydrogen bonds in the crystal structures of C3N3S3H2Na center dot 3H(2)O and C3N3S3H2Cu(PPh3)(2)

M F Mahon, K C Molloy, M M Venter, L Haiduc

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

25 Citations (SciVal)

Abstract

The monosodium salt of trithiocyanuric acid, C3N3S3H2Na, has been isolated as its trihydrate (1) by partial neutralisation of C3N3S3H3 with NaOH. Each sodium in the structure displays a novel cis-S2NaO4 coordination sphere and is hydrogen bonded to the anion, which adopts its thione form. Compound 1 has been used to synthesise other unsymmetrically-metallated trithiocyanuric acid derivatives. typified by [C3N3S3H2Cu(PPh3)(2)] and whose structure has also been determined. The nickel complex [C3N3S3H2NiCl(PPh3)(2)] (.) 0.5CH(2)Cl(2) was also obtained, but only tri-substituted compounds C3N3S3[Au(PPh3)](3) (.) 2CH(2)Cl(2) and C3N3S3(SnMe3)(3) were formed when 1 was reacted with (Ph3P)AuCl and Me3SnCl, respectively. (C) 2002 Elsevier Science B.V. All rights reserved.

Original language	English
Pages (from-to)	75-81
Number of pages	7
Journal	Inorganica Chimica Acta
Volume	348
DOIs	https://doi.org/10.1016/s0020-1693(02)01468-8
Publication status	Published - 2003

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ID number: ISI:000183004900011

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Mahon, M. F., Molloy, K. C., Venter, M. M., & Haiduc, L. (2003). Unsymmetrically-substituted 2,4,6-trimercaptotriazine: supramolecular self-assembly through C=S center dot center dot center dot H-N hydrogen bonds in the crystal structures of C3N3S3H2Na center dot 3H(2)O and C3N3S3H2Cu(PPh3)(2). Inorganica Chimica Acta, 348, 75-81. https://doi.org/10.1016/s0020-1693(02)01468-8

Unsymmetrically-substituted 2,4,6-trimercaptotriazine: supramolecular self-assembly through C=S center dot center dot center dot H-N hydrogen bonds in the crystal structures of C3N3S3H2Na center dot 3H(2)O and C3N3S3H2Cu(PPh3)(2). / Mahon, M F; Molloy, K C; Venter, M M et al.
In: Inorganica Chimica Acta, Vol. 348, 2003, p. 75-81.

Research output: Contribution to journal › Article › peer-review

Mahon, MF, Molloy, KC, Venter, MM & Haiduc, L 2003, 'Unsymmetrically-substituted 2,4,6-trimercaptotriazine: supramolecular self-assembly through C=S center dot center dot center dot H-N hydrogen bonds in the crystal structures of C3N3S3H2Na center dot 3H(2)O and C3N3S3H2Cu(PPh3)(2)', Inorganica Chimica Acta, vol. 348, pp. 75-81. https://doi.org/10.1016/s0020-1693(02)01468-8

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title = "Unsymmetrically-substituted 2,4,6-trimercaptotriazine: supramolecular self-assembly through C=S center dot center dot center dot H-N hydrogen bonds in the crystal structures of C3N3S3H2Na center dot 3H(2)O and C3N3S3H2Cu(PPh3)(2)",

abstract = "The monosodium salt of trithiocyanuric acid, C3N3S3H2Na, has been isolated as its trihydrate (1) by partial neutralisation of C3N3S3H3 with NaOH. Each sodium in the structure displays a novel cis-S2NaO4 coordination sphere and is hydrogen bonded to the anion, which adopts its thione form. Compound 1 has been used to synthesise other unsymmetrically-metallated trithiocyanuric acid derivatives. typified by [C3N3S3H2Cu(PPh3)(2)] and whose structure has also been determined. The nickel complex [C3N3S3H2NiCl(PPh3)(2)] (.) 0.5CH(2)Cl(2) was also obtained, but only tri-substituted compounds C3N3S3[Au(PPh3)](3) (.) 2CH(2)Cl(2) and C3N3S3(SnMe3)(3) were formed when 1 was reacted with (Ph3P)AuCl and Me3SnCl, respectively. (C) 2002 Elsevier Science B.V. All rights reserved.",

author = "Mahon, {M F} and Molloy, {K C} and Venter, {M M} and L Haiduc",

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T1 - Unsymmetrically-substituted 2,4,6-trimercaptotriazine: supramolecular self-assembly through C=S center dot center dot center dot H-N hydrogen bonds in the crystal structures of C3N3S3H2Na center dot 3H(2)O and C3N3S3H2Cu(PPh3)(2)

AU - Mahon, M F

AU - Molloy, K C

AU - Venter, M M

AU - Haiduc, L

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N2 - The monosodium salt of trithiocyanuric acid, C3N3S3H2Na, has been isolated as its trihydrate (1) by partial neutralisation of C3N3S3H3 with NaOH. Each sodium in the structure displays a novel cis-S2NaO4 coordination sphere and is hydrogen bonded to the anion, which adopts its thione form. Compound 1 has been used to synthesise other unsymmetrically-metallated trithiocyanuric acid derivatives. typified by [C3N3S3H2Cu(PPh3)(2)] and whose structure has also been determined. The nickel complex [C3N3S3H2NiCl(PPh3)(2)] (.) 0.5CH(2)Cl(2) was also obtained, but only tri-substituted compounds C3N3S3[Au(PPh3)](3) (.) 2CH(2)Cl(2) and C3N3S3(SnMe3)(3) were formed when 1 was reacted with (Ph3P)AuCl and Me3SnCl, respectively. (C) 2002 Elsevier Science B.V. All rights reserved.

AB - The monosodium salt of trithiocyanuric acid, C3N3S3H2Na, has been isolated as its trihydrate (1) by partial neutralisation of C3N3S3H3 with NaOH. Each sodium in the structure displays a novel cis-S2NaO4 coordination sphere and is hydrogen bonded to the anion, which adopts its thione form. Compound 1 has been used to synthesise other unsymmetrically-metallated trithiocyanuric acid derivatives. typified by [C3N3S3H2Cu(PPh3)(2)] and whose structure has also been determined. The nickel complex [C3N3S3H2NiCl(PPh3)(2)] (.) 0.5CH(2)Cl(2) was also obtained, but only tri-substituted compounds C3N3S3[Au(PPh3)](3) (.) 2CH(2)Cl(2) and C3N3S3(SnMe3)(3) were formed when 1 was reacted with (Ph3P)AuCl and Me3SnCl, respectively. (C) 2002 Elsevier Science B.V. All rights reserved.

U2 - 10.1016/s0020-1693(02)01468-8

DO - 10.1016/s0020-1693(02)01468-8

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VL - 348

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JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

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