Unprecedented double migratory insertion of phenyl isocyanide into cyclopentadienyl C–H bonds

Andrew L. Johnson; Alexander M. Willcocks; Paul R. Raithby; Mark R. Warren; Andrew J. Kingsley; Raj Odedra

doi:10.1039/b822337h

Unprecedented double migratory insertion of phenyl isocyanide into cyclopentadienyl C–H bonds

Andrew L. Johnson, Alexander M. Willcocks, Paul R. Raithby, Mark R. Warren, Andrew J. Kingsley, Raj Odedra

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12 Citations (SciVal)

Abstract

The reaction of [(η⁵-C₅H₅)Cu(CNPh)] with phenyl-isocyanide results in an unprecedented double migratory insertion into two sp² C–H bonds of a η⁵-coordinated cyclopentadienyl group, and formation of the 6-aminofulvene-2-aldimine complexes [(CNPh)Cu(κ²-N, N-C₅H₃-1,2-(CHNPh)₂)] and [(CNPh)₂Cu(κ²-N, N-C₅H₃-1,2-(CHNPh)₂)], respectively, both of which have been structurally characterised.

Original language	English
Pages (from-to)	922-924
Number of pages	3
Journal	Dalton Transactions
Volume	2009
Issue number	6
Early online date	6 Jan 2009
DOIs	https://doi.org/10.1039/b822337h
Publication status	Published - 6 Jan 2009

ASJC Scopus subject areas

General Chemistry

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10.1039/b822337h

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@article{3829ca7c36a147e7a69cf502e1a3f700,

title = "Unprecedented double migratory insertion of phenyl isocyanide into cyclopentadienyl C–H bonds",

abstract = "The reaction of [(η5-C5H5)Cu(CNPh)] with phenyl-isocyanide results in an unprecedented double migratory insertion into two sp2 C–H bonds of a η5-coordinated cyclopentadienyl group, and formation of the 6-aminofulvene-2-aldimine complexes [(CNPh)Cu(κ2-N, N-C5H3-1,2-(CHNPh)2)] and [(CNPh)2Cu(κ2-N, N-C5H3-1,2-(CHNPh)2)], respectively, both of which have been structurally characterised.",

author = "Johnson, {Andrew L.} and Willcocks, {Alexander M.} and Raithby, {Paul R.} and Warren, {Mark R.} and Kingsley, {Andrew J.} and Raj Odedra",

year = "2009",

month = jan,

day = "6",

doi = "10.1039/b822337h",

language = "English",

volume = "2009",

pages = "922--924",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "6",

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TY - JOUR

T1 - Unprecedented double migratory insertion of phenyl isocyanide into cyclopentadienyl C–H bonds

AU - Johnson, Andrew L.

AU - Willcocks, Alexander M.

AU - Raithby, Paul R.

AU - Warren, Mark R.

AU - Kingsley, Andrew J.

AU - Odedra, Raj

PY - 2009/1/6

Y1 - 2009/1/6

N2 - The reaction of [(η5-C5H5)Cu(CNPh)] with phenyl-isocyanide results in an unprecedented double migratory insertion into two sp2 C–H bonds of a η5-coordinated cyclopentadienyl group, and formation of the 6-aminofulvene-2-aldimine complexes [(CNPh)Cu(κ2-N, N-C5H3-1,2-(CHNPh)2)] and [(CNPh)2Cu(κ2-N, N-C5H3-1,2-(CHNPh)2)], respectively, both of which have been structurally characterised.

AB - The reaction of [(η5-C5H5)Cu(CNPh)] with phenyl-isocyanide results in an unprecedented double migratory insertion into two sp2 C–H bonds of a η5-coordinated cyclopentadienyl group, and formation of the 6-aminofulvene-2-aldimine complexes [(CNPh)Cu(κ2-N, N-C5H3-1,2-(CHNPh)2)] and [(CNPh)2Cu(κ2-N, N-C5H3-1,2-(CHNPh)2)], respectively, both of which have been structurally characterised.

UR - http://www.scopus.com/inward/record.url?scp=62549153075&partnerID=8YFLogxK

UR - http://dx.doi.org/10.1039/b822337h

U2 - 10.1039/b822337h

DO - 10.1039/b822337h

M3 - Article

SN - 1477-9226

VL - 2009

SP - 922

EP - 924

JO - Dalton Transactions

JF - Dalton Transactions

IS - 6

ER -

Unprecedented double migratory insertion of phenyl isocyanide into cyclopentadienyl C–H bonds

Abstract

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Senior Fellowship - TIME RESOLVED CRYSTALLOGRAPHY

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Unprecedented double migratory insertion of phenyl isocyanide into cyclopentadienyl C–H bonds

Abstract

ASJC Scopus subject areas

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Projects

Senior Fellowship - TIME RESOLVED CRYSTALLOGRAPHY

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