Ultrathin Carbon Molecular Sieve Films and Room-Temperature Oxygen Functionalization for Gas-Sieving

Shiqi Huang, Luis francisco Villalobos, Deepu j. Babu, Guangwei He, Mo Li, Andreas Züttel, Kumar varoon Agrawal

Research output: Contribution to journalArticlepeer-review

18 Citations (SciVal)

Abstract

Inorganic membranes based on carbon molecular sieve (CMS) films hosting slit-like pores can yield high molecular selectivity with a sub-angstrom resolution in molecular differentiation and therefore are highly attractive for energy-efficient separations. However, the selective layer thickness of the state-of-the-art CMS membranes for gas separation is more than 1 μm, yielding low gas permeance. Also, there is no room-temperature functionalization route for the modification of the pore-size-distribution of CMS to increase the molecular selectivity. In this context, we report two novel fabrication routes, namely, transfer and masking techniques, leading to CMS films with thicknesses as small as 100 nm, yielding attractive gas-sieving performances with H2 permeance reaching up to 3060 gas permeation unit (GPU). Further, a rapid and highly tunable room-temperature ozone treatment-based postsynthetic modification is reported, shrinking the electron density gap in the nanopores by a fraction of an angstrom and improving gas selectivities by several folds. The optimized membranes yielded H2 permeance of 507 GPU and H2/CH4 selectivity of 50.7.
Original languageEnglish
Pages (from-to)16729-16736
JournalACS applied materials & interfaces
Volume11
Issue number18
DOIs
Publication statusPublished - 8 May 2019
Externally publishedYes

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