Two triorganostannate complexes synthesised from bis(cyclopentadienyl)tin(II); structural variation between [Mg(thf)6]2+2[Sn(η3-C5H 5)3]- and [Li(thf)4]+ [Sn(C13H9)3]- (thf = tetrahydrofuran, C13H9 = fluorenyl)

Andrew J. Edwards; Michael A. Paver; Paul R. Raithby; Christopher A. Russell; Dietmar Stalke; Alexander Steiner; Dominic S. Wright

doi:10.1039/DT9930001465

Two triorganostannate complexes synthesised from bis(cyclopentadienyl)tin(II); structural variation between [Mg(thf)₆]²⁺2[Sn(η³-C₅H ₅)₃]^- and [Li(thf)₄]⁺ [Sn(C₁₃H₉)₃]^- (thf = tetrahydrofuran, C₁₃H₉ = fluorenyl)

Andrew J. Edwards
, Michael A. Paver
, Paul R. Raithby
, Christopher A. Russell
, Dietmar Stalke
, Alexander Steiner
, Dominic S. Wright

University of Cambridge
Institut für Anorganische Chemie

Research output: Contribution to journal › Article › peer-review

Abstract

Nucleophilic addition of Mg(C₅H₅)₂ to Sn(C₅H₅)₂ (1:2) in tetrahydrofuran (thf) gave [Mg(thf)₆]²⁺ 2[Sn(η³-C₅H₅)₃]₂ 1 whereas the reaction of fluorenyllithium (2 or 3 equivalents) resulted in nucleophilic substitution of both C₅H₅ ligands and in the formation of [Li(thf)₄]⁺ [Sn(C₁₃H₉)₃]^- 2; the anion of 1 is essentially planar whereas that in 2 has a distorted-pyramidal structure.

Original language	English
Pages (from-to)	1465-1466
Number of pages	2
Journal	Journal of the Chemical Society, Dalton Transactions
Issue number	9
DOIs	https://doi.org/10.1039/DT9930001465
Publication status	Published - 1993

ASJC Scopus subject areas

General Chemistry

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Edwards, A. J., Paver, M. A., Raithby, P. R., Russell, C. A., Stalke, D., Steiner, A., & Wright, D. S. (1993). Two triorganostannate complexes synthesised from bis(cyclopentadienyl)tin(II); structural variation between [Mg(thf)₆]²⁺2[Sn(η³-C₅H ₅)₃]^- and [Li(thf)₄]⁺ [Sn(C₁₃H₉)₃]^- (thf = tetrahydrofuran, C₁₃H₉ = fluorenyl). Journal of the Chemical Society, Dalton Transactions, (9), 1465-1466. https://doi.org/10.1039/DT9930001465

Two triorganostannate complexes synthesised from bis(cyclopentadienyl)tin(II); structural variation between [Mg(thf)₆]²⁺2[Sn(η³-C₅H ₅)₃]^- and [Li(thf)₄]⁺ [Sn(C₁₃H₉)₃]^- (thf = tetrahydrofuran, C₁₃H₉ = fluorenyl). / Edwards, Andrew J.; Paver, Michael A.; Raithby, Paul R. et al.
In: Journal of the Chemical Society, Dalton Transactions, No. 9, 1993, p. 1465-1466.

Research output: Contribution to journal › Article › peer-review

Edwards, AJ, Paver, MA, Raithby, PR, Russell, CA, Stalke, D, Steiner, A & Wright, DS 1993, 'Two triorganostannate complexes synthesised from bis(cyclopentadienyl)tin(II); structural variation between [Mg(thf)₆]²⁺2[Sn(η³-C₅H ₅)₃]^- and [Li(thf)₄]⁺ [Sn(C₁₃H₉)₃]^- (thf = tetrahydrofuran, C₁₃H₉ = fluorenyl)', Journal of the Chemical Society, Dalton Transactions, no. 9, pp. 1465-1466. https://doi.org/10.1039/DT9930001465

Edwards AJ, Paver MA, Raithby PR, Russell CA, Stalke D, Steiner A et al. Two triorganostannate complexes synthesised from bis(cyclopentadienyl)tin(II); structural variation between [Mg(thf)₆]²⁺2[Sn(η³-C₅H ₅)₃]^- and [Li(thf)₄]⁺ [Sn(C₁₃H₉)₃]^- (thf = tetrahydrofuran, C₁₃H₉ = fluorenyl). Journal of the Chemical Society, Dalton Transactions. 1993;(9):1465-1466. doi: 10.1039/DT9930001465

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abstract = "Nucleophilic addition of Mg(C5H5)2 to Sn(C5H5)2 (1:2) in tetrahydrofuran (thf) gave [Mg(thf)6]2+ 2[Sn(η3-C5H5)3]2 1 whereas the reaction of fluorenyllithium (2 or 3 equivalents) resulted in nucleophilic substitution of both C5H5 ligands and in the formation of [Li(thf)4]+ [Sn(C13H9)3]- 2; the anion of 1 is essentially planar whereas that in 2 has a distorted-pyramidal structure.",

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