Two-electron addition reactions and reversible carbonylation of an unsaturated pentanuclear osmium complex; x-ray crystal structure of [Os 5(CO)13H(PhNC6H4N)(PEt3)]

Zain Dawoodi; Martin J. Mays; Paul R. Raithby

doi:10.1039/C39810000801

Two-electron addition reactions and reversible carbonylation of an unsaturated pentanuclear osmium complex; x-ray crystal structure of [Os ₅(CO)₁₃H(PhNC₆H₄N)(PEt₃)]

Zain Dawoodi, Martin J. Mays, Paul R. Raithby

University of Cambridge

Research output: Contribution to journal › Article › peer-review

Abstract

Reaction of [Os₅(CO)₁₃H(PhNC₆H ₄N)] with L = PEt₃, CNBu^t, and CO yields 1:1 addition products of the type [Os₅(CO)₁₃H(PhNC ₆H₄N)L], the reaction with CO being reversible; the structure of the PEt₃ adduct has been established by an X-ray structural analysis.

Original language	English
Pages (from-to)	801-803
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	15
DOIs	https://doi.org/10.1039/C39810000801
Publication status	Published - 1981

ASJC Scopus subject areas

Molecular Medicine

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Two-electron addition reactions and reversible carbonylation of an unsaturated pentanuclear osmium complex; x-ray crystal structure of [Os ₅(CO)₁₃H(PhNC₆H₄N)(PEt₃)]. / Dawoodi, Zain; Mays, Martin J.; Raithby, Paul R.
In: Journal of the Chemical Society, Chemical Communications, No. 15, 1981, p. 801-803.

Research output: Contribution to journal › Article › peer-review

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title = "Two-electron addition reactions and reversible carbonylation of an unsaturated pentanuclear osmium complex; x-ray crystal structure of [Os 5(CO)13H(PhNC6H4N)(PEt3)]",

abstract = "Reaction of [Os5(CO)13H(PhNC6H 4N)] with L = PEt3, CNBut, and CO yields 1:1 addition products of the type [Os5(CO)13H(PhNC 6H4N)L], the reaction with CO being reversible; the structure of the PEt3 adduct has been established by an X-ray structural analysis.",

author = "Zain Dawoodi and Mays, \{Martin J.\} and Raithby, \{Paul R.\}",

year = "1981",

doi = "10.1039/C39810000801",

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journal = "Journal of the Chemical Society, Chemical Communications",

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AU - Dawoodi, Zain

AU - Mays, Martin J.

AU - Raithby, Paul R.

PY - 1981

Y1 - 1981

N2 - Reaction of [Os5(CO)13H(PhNC6H 4N)] with L = PEt3, CNBut, and CO yields 1:1 addition products of the type [Os5(CO)13H(PhNC 6H4N)L], the reaction with CO being reversible; the structure of the PEt3 adduct has been established by an X-ray structural analysis.

AB - Reaction of [Os5(CO)13H(PhNC6H 4N)] with L = PEt3, CNBut, and CO yields 1:1 addition products of the type [Os5(CO)13H(PhNC 6H4N)L], the reaction with CO being reversible; the structure of the PEt3 adduct has been established by an X-ray structural analysis.

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JF - Journal of the Chemical Society, Chemical Communications

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Two-electron addition reactions and reversible carbonylation of an unsaturated pentanuclear osmium complex; x-ray crystal structure of [Os ₅(CO)₁₃H(PhNC₆H₄N)(PEt₃)]

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