Tris(triorganostannyltetrazoles): Synthesis and supramolecular structures

Michael Hill, Mary F. Mahon, Kieran C. Molloy

Research output: Contribution to journalArticlepeer-review

78 Citations (Scopus)

Abstract

Six trifunctional triorganotin tetrazoles, (R3SnN4CCH2CH2)3C(NO 2) and 1,3,5-(R3SnN4C)3C6H3(R = Me, Et or Bu), have been synthesised by a cycloaddition route from SnR3(N3) and either (NCCH2CH2)3C(NO2) or 1,3,5-(NC)3C6H3 as dipblarophile. The compounds have been characterised by 1H, 13C, 119Sn NMR and 119Mössbauer spectroscopies, while the crystal structures of the tributyltin examples of each series reveal they adopt layered supramolecular arrays.

Original languageEnglish
Pages (from-to)1857-1865
Number of pages9
JournalJournal of the Chemical Society - Dalton Transactions
Issue number9
DOIs
Publication statusPublished - 7 May 1996

ASJC Scopus subject areas

  • Chemistry(all)

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