Trimethyltriazacyclohexane as bridging ligand for triangular Cu-3 units and C-H hydride abstraction into a Cu-6 cluster

R D Kohn; Z Pan; M F Mahon; G Kociok-Kohn

doi:10.1039/b302670a

Trimethyltriazacyclohexane as bridging ligand for triangular Cu-3 units and C-H hydride abstraction into a Cu-6 cluster

R D Kohn, Z Pan, M F Mahon, G Kociok-Kohn

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

36 Citations (SciVal)

Abstract

Reaction of [Cu(MeCN)(4)](BF4) with N,N',N"-trimethyl-1,3,5- triazacyclohexane in CH2Cl2 leads to two Cu-6 clusters containing the triazacyclohexane as a ligand to triangular Cu-3 units with the abstraction and incorporation of chloride and hydride.

Original language	English
Pages (from-to)	1272-1273
Number of pages	2
Journal	Chemical Communications
Issue number	11
DOIs	https://doi.org/10.1039/b302670a
Publication status	Published - 2003

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ID number: ISI:000182931700027

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10.1039/b302670a

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title = "Trimethyltriazacyclohexane as bridging ligand for triangular Cu-3 units and C-H hydride abstraction into a Cu-6 cluster",

abstract = "Reaction of [Cu(MeCN)(4)](BF4) with N,N',N{"}-trimethyl-1,3,5- triazacyclohexane in CH2Cl2 leads to two Cu-6 clusters containing the triazacyclohexane as a ligand to triangular Cu-3 units with the abstraction and incorporation of chloride and hydride.",

author = "Kohn, {R D} and Z Pan and Mahon, {M F} and G Kociok-Kohn",

note = "ID number: ISI:000182931700027",

year = "2003",

doi = "10.1039/b302670a",

language = "English",

pages = "1272--1273",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "11",

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TY - JOUR

T1 - Trimethyltriazacyclohexane as bridging ligand for triangular Cu-3 units and C-H hydride abstraction into a Cu-6 cluster

AU - Kohn, R D

AU - Pan, Z

AU - Mahon, M F

AU - Kociok-Kohn, G

N1 - ID number: ISI:000182931700027

PY - 2003

Y1 - 2003

N2 - Reaction of [Cu(MeCN)(4)](BF4) with N,N',N"-trimethyl-1,3,5- triazacyclohexane in CH2Cl2 leads to two Cu-6 clusters containing the triazacyclohexane as a ligand to triangular Cu-3 units with the abstraction and incorporation of chloride and hydride.

AB - Reaction of [Cu(MeCN)(4)](BF4) with N,N',N"-trimethyl-1,3,5- triazacyclohexane in CH2Cl2 leads to two Cu-6 clusters containing the triazacyclohexane as a ligand to triangular Cu-3 units with the abstraction and incorporation of chloride and hydride.

U2 - 10.1039/b302670a

DO - 10.1039/b302670a

M3 - Article

SN - 1359-7345

SP - 1272

EP - 1273

JO - Chemical Communications

JF - Chemical Communications

IS - 11

ER -

Trimethyltriazacyclohexane as bridging ligand for triangular Cu-3 units and C-H hydride abstraction into a Cu-6 cluster

Abstract

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