Trimethyltriazacyclohexane as bridging ligand for triangular Cu-3 units and C-H hydride abstraction into a Cu-6 cluster

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Abstract

Reaction of [Cu(MeCN)(4)](BF4) with N,N',N"-trimethyl-1,3,5- triazacyclohexane in CH2Cl2 leads to two Cu-6 clusters containing the triazacyclohexane as a ligand to triangular Cu-3 units with the abstraction and incorporation of chloride and hydride.
Original languageEnglish
Pages (from-to)1272-1273
Number of pages2
JournalChemical Communications
Issue number11
DOIs
Publication statusPublished - 2003

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Hydrides
Chlorides
Ligands
Hydrogen

Cite this

@article{3469cf2957964bcba426986871c70977,
title = "Trimethyltriazacyclohexane as bridging ligand for triangular Cu-3 units and C-H hydride abstraction into a Cu-6 cluster",
abstract = "Reaction of [Cu(MeCN)(4)](BF4) with N,N',N{"}-trimethyl-1,3,5- triazacyclohexane in CH2Cl2 leads to two Cu-6 clusters containing the triazacyclohexane as a ligand to triangular Cu-3 units with the abstraction and incorporation of chloride and hydride.",
author = "Kohn, {R D} and Z Pan and Mahon, {M F} and G Kociok-Kohn",
note = "ID number: ISI:000182931700027",
year = "2003",
doi = "10.1039/b302670a",
language = "English",
pages = "1272--1273",
journal = "Chemical communications (Cambridge, England)",
issn = "1359-7345",
publisher = "Royal Society of Chemistry",
number = "11",

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TY - JOUR

T1 - Trimethyltriazacyclohexane as bridging ligand for triangular Cu-3 units and C-H hydride abstraction into a Cu-6 cluster

AU - Kohn, R D

AU - Pan, Z

AU - Mahon, M F

AU - Kociok-Kohn, G

N1 - ID number: ISI:000182931700027

PY - 2003

Y1 - 2003

N2 - Reaction of [Cu(MeCN)(4)](BF4) with N,N',N"-trimethyl-1,3,5- triazacyclohexane in CH2Cl2 leads to two Cu-6 clusters containing the triazacyclohexane as a ligand to triangular Cu-3 units with the abstraction and incorporation of chloride and hydride.

AB - Reaction of [Cu(MeCN)(4)](BF4) with N,N',N"-trimethyl-1,3,5- triazacyclohexane in CH2Cl2 leads to two Cu-6 clusters containing the triazacyclohexane as a ligand to triangular Cu-3 units with the abstraction and incorporation of chloride and hydride.

U2 - 10.1039/b302670a

DO - 10.1039/b302670a

M3 - Article

SP - 1272

EP - 1273

JO - Chemical communications (Cambridge, England)

JF - Chemical communications (Cambridge, England)

SN - 1359-7345

IS - 11

ER -