Trifluoromethyl coordination and C-F bond activation at calcium

Anthony G.M. Barrett; Mark R. Crimmin; Michael S. Hill; Peter B. Hitchcock; Panayiotis A. Procopiou

doi:10.1002/anie.200701945

Trifluoromethyl coordination and C-F bond activation at calcium

Anthony G.M. Barrett, Mark R. Crimmin, Michael S. Hill, Peter B. Hitchcock, Panayiotis A. Procopiou

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

72 Citations (SciVal)

Abstract

(Chemical Equation Presented) Fluoral arrangement: The calcium β-diketiminate complex 1 (see scheme) not only exhibits an unexpected and unprecedented binding mode of a CF₃ group, from which one fluorine atom coordinates to the Ca center, but also undergoes C-F bond cleavage through the formation of a heteroleptic calcium fluoride complex.

Original language	English
Pages (from-to)	6339-6342
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	46
Issue number	33
DOIs	https://doi.org/10.1002/anie.200701945
Publication status	Published - 3 Sept 2007

Keywords

Alkaline earth metals
C-F activation
Calcium
Fluorine
N ligands

ASJC Scopus subject areas

Catalysis
General Chemistry

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10.1002/anie.200701945

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abstract = "(Chemical Equation Presented) Fluoral arrangement: The calcium β-diketiminate complex 1 (see scheme) not only exhibits an unexpected and unprecedented binding mode of a CF3 group, from which one fluorine atom coordinates to the Ca center, but also undergoes C-F bond cleavage through the formation of a heteroleptic calcium fluoride complex.",

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AU - Crimmin, Mark R.

AU - Hill, Michael S.

AU - Hitchcock, Peter B.

AU - Procopiou, Panayiotis A.

PY - 2007/9/3

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N2 - (Chemical Equation Presented) Fluoral arrangement: The calcium β-diketiminate complex 1 (see scheme) not only exhibits an unexpected and unprecedented binding mode of a CF3 group, from which one fluorine atom coordinates to the Ca center, but also undergoes C-F bond cleavage through the formation of a heteroleptic calcium fluoride complex.

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KW - Alkaline earth metals

KW - C-F activation

KW - Calcium

KW - Fluorine

KW - N ligands

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Trifluoromethyl coordination and C-F bond activation at calcium

Abstract

Keywords

ASJC Scopus subject areas

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