Trifluoromethyl coordination and C-F bond activation at calcium

Anthony G.M. Barrett; Mark R. Crimmin; Michael S. Hill; Peter B. Hitchcock; Panayiotis A. Procopiou

doi:10.1002/anie.200701945

Trifluoromethyl coordination and C-F bond activation at calcium

Anthony G.M. Barrett
, Mark R. Crimmin
, Michael S. Hill
, Peter B. Hitchcock
, Panayiotis A. Procopiou

Department of Chemistry

Imperial College London
University of Sussex
GlaxoSmithKline

Research output: Contribution to journal › Article › peer-review

74 Citations (SciVal)

Abstract

(Chemical Equation Presented) Fluoral arrangement: The calcium β-diketiminate complex 1 (see scheme) not only exhibits an unexpected and unprecedented binding mode of a CF₃ group, from which one fluorine atom coordinates to the Ca center, but also undergoes C-F bond cleavage through the formation of a heteroleptic calcium fluoride complex.

Original language	English
Pages (from-to)	6339-6342
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	46
Issue number	33
DOIs	https://doi.org/10.1002/anie.200701945
Publication status	Published - 3 Sept 2007

Keywords

Alkaline earth metals
C-F activation
Calcium
Fluorine
N ligands

ASJC Scopus subject areas

Catalysis
General Chemistry

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10.1002/anie.200701945

Cite this

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title = "Trifluoromethyl coordination and C-F bond activation at calcium",

abstract = "(Chemical Equation Presented) Fluoral arrangement: The calcium β-diketiminate complex 1 (see scheme) not only exhibits an unexpected and unprecedented binding mode of a CF3 group, from which one fluorine atom coordinates to the Ca center, but also undergoes C-F bond cleavage through the formation of a heteroleptic calcium fluoride complex.",

keywords = "Alkaline earth metals, C-F activation, Calcium, Fluorine, N ligands",

author = "Barrett, \{Anthony G.M.\} and Crimmin, \{Mark R.\} and Hill, \{Michael S.\} and Hitchcock, \{Peter B.\} and Procopiou, \{Panayiotis A.\}",

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doi = "10.1002/anie.200701945",

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AU - Barrett, Anthony G.M.

AU - Crimmin, Mark R.

AU - Hill, Michael S.

AU - Hitchcock, Peter B.

AU - Procopiou, Panayiotis A.

PY - 2007/9/3

Y1 - 2007/9/3

N2 - (Chemical Equation Presented) Fluoral arrangement: The calcium β-diketiminate complex 1 (see scheme) not only exhibits an unexpected and unprecedented binding mode of a CF3 group, from which one fluorine atom coordinates to the Ca center, but also undergoes C-F bond cleavage through the formation of a heteroleptic calcium fluoride complex.

AB - (Chemical Equation Presented) Fluoral arrangement: The calcium β-diketiminate complex 1 (see scheme) not only exhibits an unexpected and unprecedented binding mode of a CF3 group, from which one fluorine atom coordinates to the Ca center, but also undergoes C-F bond cleavage through the formation of a heteroleptic calcium fluoride complex.

KW - Alkaline earth metals

KW - C-F activation

KW - Calcium

KW - Fluorine

KW - N ligands

UR - https://www.scopus.com/pages/publications/34548273957

U2 - 10.1002/anie.200701945

DO - 10.1002/anie.200701945

M3 - Article

C2 - 17640022

AN - SCOPUS:34548273957

SN - 1433-7851

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SP - 6339

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 33

ER -

Trifluoromethyl coordination and C-F bond activation at calcium

Abstract

Keywords

ASJC Scopus subject areas

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