Abstract
(Chemical Equation Presented) Fluoral arrangement: The calcium β-diketiminate complex 1 (see scheme) not only exhibits an unexpected and unprecedented binding mode of a CF3 group, from which one fluorine atom coordinates to the Ca center, but also undergoes C-F bond cleavage through the formation of a heteroleptic calcium fluoride complex.
Original language | English |
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Pages (from-to) | 6339-6342 |
Number of pages | 4 |
Journal | Angewandte Chemie - International Edition |
Volume | 46 |
Issue number | 33 |
DOIs | |
Publication status | Published - 3 Sept 2007 |
Keywords
- Alkaline earth metals
- C-F activation
- Calcium
- Fluorine
- N ligands
ASJC Scopus subject areas
- Catalysis
- General Chemistry