Transport, trapping and interfacial transfer of electrons in dye-sensitized nanocrystalline solar cells

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Abstract

The physical and chemical processes taking place in dye-sensitized solar cells (DSC) are reviewed. In order to achieve high power efficiencies under solar irradiation, it is essential to incorporate kinetic asymmetry into the design of DSCs. Electron transfer to the redox mediator should be slow from the nanocrystalline oxide and fast from the regenerating electrode. This asymmetry can be achieved by the choice of redox electrolyte as well as by selective use of electrocatalysis to accelerate electron transfer at one contact and suitable blocking layers to retard electron transfer at the other interfaces. In the discussion of the processes that determine the efficiency of DSCs, particular emphasis is placed on the role of electron trapping in determining the rates of electron transport and interfacial electron transfer. The prospects for improving the performance of DSCs are discussed in a quantitative framework based on current understanding of the cells. (c) 2006 Elsevier B.V. All rights reserved.
LanguageEnglish
Pages233-240
Number of pages8
JournalJournal of Electroanalytical Chemistry
Volume599
Issue number2
DOIs
StatusPublished - 2007

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Solar cells
Coloring Agents
Dyes
Electrons
Electrocatalysis
Oxides
Electrolytes
Irradiation
Electrodes
Kinetics
Oxidation-Reduction

Cite this

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title = "Transport, trapping and interfacial transfer of electrons in dye-sensitized nanocrystalline solar cells",
abstract = "The physical and chemical processes taking place in dye-sensitized solar cells (DSC) are reviewed. In order to achieve high power efficiencies under solar irradiation, it is essential to incorporate kinetic asymmetry into the design of DSCs. Electron transfer to the redox mediator should be slow from the nanocrystalline oxide and fast from the regenerating electrode. This asymmetry can be achieved by the choice of redox electrolyte as well as by selective use of electrocatalysis to accelerate electron transfer at one contact and suitable blocking layers to retard electron transfer at the other interfaces. In the discussion of the processes that determine the efficiency of DSCs, particular emphasis is placed on the role of electron trapping in determining the rates of electron transport and interfacial electron transfer. The prospects for improving the performance of DSCs are discussed in a quantitative framework based on current understanding of the cells. (c) 2006 Elsevier B.V. All rights reserved.",
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AB - The physical and chemical processes taking place in dye-sensitized solar cells (DSC) are reviewed. In order to achieve high power efficiencies under solar irradiation, it is essential to incorporate kinetic asymmetry into the design of DSCs. Electron transfer to the redox mediator should be slow from the nanocrystalline oxide and fast from the regenerating electrode. This asymmetry can be achieved by the choice of redox electrolyte as well as by selective use of electrocatalysis to accelerate electron transfer at one contact and suitable blocking layers to retard electron transfer at the other interfaces. In the discussion of the processes that determine the efficiency of DSCs, particular emphasis is placed on the role of electron trapping in determining the rates of electron transport and interfacial electron transfer. The prospects for improving the performance of DSCs are discussed in a quantitative framework based on current understanding of the cells. (c) 2006 Elsevier B.V. All rights reserved.

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