Transition metal versus heavy metal synergy in selective catalytic oxidations

Matthew E. Potter, A. James Paterson, Robert Raja

Research output: Contribution to journalArticlepeer-review

20 Citations (SciVal)

Abstract

Simultaneous framework incorporation of heavy metal ions such as Ru(III) and Sn(IV) into aluminophosphate architectures generates novel bimetallic active sites, which facilitate synergistic interactions, affording high degrees of selectivity and activity in the catalytic oxidations as compared with analogous bimetallic systems, in which transition metals, such as Co(III) and Ti(IV), have been similarly incorporated.

Original languageEnglish
Pages (from-to)2446-2451
Number of pages6
JournalACS Catalysis
Volume2
Issue number12
Early online date31 Oct 2012
DOIs
Publication statusPublished - 7 Dec 2012

Keywords

  • catalytic synergy
  • microporous solids
  • multifunctional active sites
  • oxidation
  • redox catalysts

ASJC Scopus subject areas

  • Catalysis
  • General Chemistry

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