Transformations of a μ2-vinyl ligand at a dimanganese centre and the flexibility of μ2-acyl ligands; x-ray crystal structures of [(Ph3P)2N][Mn2(μ2-H) ...

Kim Henrick; Jonathan A. Iggo; Martin J. Mays; Paul R. Raithby

doi:10.1039/C39840000209

Transformations of a μ₂-vinyl ligand at a dimanganese centre and the flexibility of μ₂-acyl ligands; x-ray crystal structures of [(Ph₃P)₂N][Mn₂(μ₂-H) ...

Kim Henrick, Jonathan A. Iggo, Martin J. Mays, Paul R. Raithby

Research output: Contribution to journal › Article › peer-review

Abstract

full title:Transformations of a μ₂-vinyl ligand at a dimanganese centre and the flexibility of μ₂-acyl ligands; x-ray crystal structures of [(Ph₃P)₂N][Mn₂(μ₂-H) {μ₂-C(O)CPh:CHPh}(μ₂-PPh₂)(CO) ₆], [Mn₂{μ₂-C(O)CPh:CHPh}(μ₂-PPh₂)(CO)₆(CNBu^t)₂], and [Mn₂{σ:η³-P(Ph)₂CH:CH₂}(CO)₇(PEt₃)] [Mn₂(μ₂-σ:η²-CR:CHR) (μ₂-PPh₂)(CO)₇] (R = H or Ph) reacts with 2-electron donor ligands to give μ₂-acyl complexes or products containing the P(Ph)₂CR:CHR ligand; these correspond, respectively, to insertion of CO or PPh₂ into the σ-bond between the metal and the μ₂-vinyl group.

Original language	English
Pages (from-to)	209-211
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	4
DOIs	https://doi.org/10.1039/C39840000209
Publication status	Published - 31 Dec 1984

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Molecular Medicine

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Transformations of a μ₂-vinyl ligand at a dimanganese centre and the flexibility of μ₂-acyl ligands; x-ray crystal structures of [(Ph₃P)₂N][Mn₂(μ₂-H) ... / Henrick, Kim; Iggo, Jonathan A.; Mays, Martin J. et al.
In: Journal of the Chemical Society, Chemical Communications, No. 4, 31.12.1984, p. 209-211.

Research output: Contribution to journal › Article › peer-review

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title = "Transformations of a μ2-vinyl ligand at a dimanganese centre and the flexibility of μ2-acyl ligands; x-ray crystal structures of [(Ph3P)2N][Mn2(μ2-H) ...",

abstract = "full title:Transformations of a μ2-vinyl ligand at a dimanganese centre and the flexibility of μ2-acyl ligands; x-ray crystal structures of [(Ph3P)2N][Mn2(μ2-H) {μ2-C(O)CPh:CHPh}(μ2-PPh2)(CO) 6], [Mn2{μ2-C(O)CPh:CHPh}(μ2-PPh 2)(CO)6(CNBut)2], and [Mn2{σ:η3-P(Ph)2CH:CH2 }(CO)7(PEt3)] [Mn2(μ2-σ:η2-CR:CHR) (μ2-PPh2)(CO)7] (R = H or Ph) reacts with 2-electron donor ligands to give μ2-acyl complexes or products containing the P(Ph)2CR:CHR ligand; these correspond, respectively, to insertion of CO or PPh2 into the σ-bond between the metal and the μ2-vinyl group.",

author = "Kim Henrick and Iggo, {Jonathan A.} and Mays, {Martin J.} and Raithby, {Paul R.}",

year = "1984",

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AU - Henrick, Kim

AU - Iggo, Jonathan A.

AU - Mays, Martin J.

AU - Raithby, Paul R.

PY - 1984/12/31

Y1 - 1984/12/31

N2 - full title:Transformations of a μ2-vinyl ligand at a dimanganese centre and the flexibility of μ2-acyl ligands; x-ray crystal structures of [(Ph3P)2N][Mn2(μ2-H) {μ2-C(O)CPh:CHPh}(μ2-PPh2)(CO) 6], [Mn2{μ2-C(O)CPh:CHPh}(μ2-PPh 2)(CO)6(CNBut)2], and [Mn2{σ:η3-P(Ph)2CH:CH2 }(CO)7(PEt3)] [Mn2(μ2-σ:η2-CR:CHR) (μ2-PPh2)(CO)7] (R = H or Ph) reacts with 2-electron donor ligands to give μ2-acyl complexes or products containing the P(Ph)2CR:CHR ligand; these correspond, respectively, to insertion of CO or PPh2 into the σ-bond between the metal and the μ2-vinyl group.

AB - full title:Transformations of a μ2-vinyl ligand at a dimanganese centre and the flexibility of μ2-acyl ligands; x-ray crystal structures of [(Ph3P)2N][Mn2(μ2-H) {μ2-C(O)CPh:CHPh}(μ2-PPh2)(CO) 6], [Mn2{μ2-C(O)CPh:CHPh}(μ2-PPh 2)(CO)6(CNBut)2], and [Mn2{σ:η3-P(Ph)2CH:CH2 }(CO)7(PEt3)] [Mn2(μ2-σ:η2-CR:CHR) (μ2-PPh2)(CO)7] (R = H or Ph) reacts with 2-electron donor ligands to give μ2-acyl complexes or products containing the P(Ph)2CR:CHR ligand; these correspond, respectively, to insertion of CO or PPh2 into the σ-bond between the metal and the μ2-vinyl group.

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Transformations of a μ₂-vinyl ligand at a dimanganese centre and the flexibility of μ₂-acyl ligands; x-ray crystal structures of [(Ph₃P)₂N][Mn₂(μ₂-H) ...

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