Transformation of an eta(1)-coordinated phosphaalkyne into a bridging phosphinidene ligand

C D Andrews; A D Burrows; M Green; J M Lynam; M F Mahon

doi:10.1016/j.jorganchem.2006.03.014

Transformation of an eta(1)-coordinated phosphaalkyne into a bridging phosphinidene ligand

C D Andrews, A D Burrows, M Green, J M Lynam, M F Mahon

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

2 Citations (SciVal)

Abstract

The tripalladium cluster [Pd-3( mu(3)-CO)( mu-dppm)(3)](PF6)(2) (1) reacts with two equivalents of (BuCP)-Bu-t to give [Pd-3(mu-dppm)(3)(eta(1)-PCBut)(2)](PF6)(2) (2). Prolonged storage of acetone solutions of 2 only resulted in the isolation of [Pd-3(mu-dppm)(3)(eta(1):mu(3)-PCH2But)(OCMC2)](PF6)(2) (3). Compound 3 has been characterized by X-ray crystallography. (c) 2006 Elsevier B.V. All rights reserved.

Original language	English
Pages (from-to)	2859-2862
Number of pages	4
Journal	Journal of Organometallic Chemistry
Volume	691
Issue number	13
DOIs	https://doi.org/10.1016/j.jorganchem.2006.03.014
Publication status	Published - 2006

Bibliographical note

ID number: ISI:000238309200001

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10.1016/j.jorganchem.2006.03.014

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@article{09b9a0bddbe84fbe94042cb952bb77b8,

title = "Transformation of an eta(1)-coordinated phosphaalkyne into a bridging phosphinidene ligand",

abstract = "The tripalladium cluster [Pd-3( mu(3)-CO)( mu-dppm)(3)](PF6)(2) (1) reacts with two equivalents of (BuCP)-Bu-t to give [Pd-3(mu-dppm)(3)(eta(1)-PCBut)(2)](PF6)(2) (2). Prolonged storage of acetone solutions of 2 only resulted in the isolation of [Pd-3(mu-dppm)(3)(eta(1):mu(3)-PCH2But)(OCMC2)](PF6)(2) (3). Compound 3 has been characterized by X-ray crystallography. (c) 2006 Elsevier B.V. All rights reserved.",

author = "Andrews, \{C D\} and Burrows, \{A D\} and M Green and Lynam, \{J M\} and Mahon, \{M F\}",

note = "ID number: ISI:000238309200001",

year = "2006",

doi = "10.1016/j.jorganchem.2006.03.014",

language = "English",

volume = "691",

pages = "2859--2862",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier B.V.",

number = "13",

}

TY - JOUR

T1 - Transformation of an eta(1)-coordinated phosphaalkyne into a bridging phosphinidene ligand

AU - Andrews, C D

AU - Burrows, A D

AU - Green, M

AU - Lynam, J M

AU - Mahon, M F

N1 - ID number: ISI:000238309200001

PY - 2006

Y1 - 2006

N2 - The tripalladium cluster [Pd-3( mu(3)-CO)( mu-dppm)(3)](PF6)(2) (1) reacts with two equivalents of (BuCP)-Bu-t to give [Pd-3(mu-dppm)(3)(eta(1)-PCBut)(2)](PF6)(2) (2). Prolonged storage of acetone solutions of 2 only resulted in the isolation of [Pd-3(mu-dppm)(3)(eta(1):mu(3)-PCH2But)(OCMC2)](PF6)(2) (3). Compound 3 has been characterized by X-ray crystallography. (c) 2006 Elsevier B.V. All rights reserved.

AB - The tripalladium cluster [Pd-3( mu(3)-CO)( mu-dppm)(3)](PF6)(2) (1) reacts with two equivalents of (BuCP)-Bu-t to give [Pd-3(mu-dppm)(3)(eta(1)-PCBut)(2)](PF6)(2) (2). Prolonged storage of acetone solutions of 2 only resulted in the isolation of [Pd-3(mu-dppm)(3)(eta(1):mu(3)-PCH2But)(OCMC2)](PF6)(2) (3). Compound 3 has been characterized by X-ray crystallography. (c) 2006 Elsevier B.V. All rights reserved.

UR - https://www.scopus.com/pages/publications/33646578502

U2 - 10.1016/j.jorganchem.2006.03.014

DO - 10.1016/j.jorganchem.2006.03.014

M3 - Article

SN - 0022-328X

VL - 691

SP - 2859

EP - 2862

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 13

ER -

Transformation of an eta(1)-coordinated phosphaalkyne into a bridging phosphinidene ligand

Abstract

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