Transformation of an eta(1)-coordinated phosphaalkyne into a bridging phosphinidene ligand

C D Andrews, A D Burrows, M Green, J M Lynam, M F Mahon

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

The tripalladium cluster [Pd-3( mu(3)-CO)( mu-dppm)(3)](PF6)(2) (1) reacts with two equivalents of (BuCP)-Bu-t to give [Pd-3(mu-dppm)(3)(eta(1)-PCBut)(2)](PF6)(2) (2). Prolonged storage of acetone solutions of 2 only resulted in the isolation of [Pd-3(mu-dppm)(3)(eta(1):mu(3)-PCH2But)(OCMC2)](PF6)(2) (3). Compound 3 has been characterized by X-ray crystallography. (c) 2006 Elsevier B.V. All rights reserved.
Original languageEnglish
Pages (from-to)2859-2862
Number of pages4
JournalJournal of Organometallic Chemistry
Volume691
Issue number13
DOIs
Publication statusPublished - 2006

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X ray crystallography
X Ray Crystallography
Carbon Monoxide
Acetone
acetone
crystallography
isolation
Ligands
ligands
x rays

Cite this

Transformation of an eta(1)-coordinated phosphaalkyne into a bridging phosphinidene ligand. / Andrews, C D; Burrows, A D; Green, M; Lynam, J M; Mahon, M F.

In: Journal of Organometallic Chemistry, Vol. 691, No. 13, 2006, p. 2859-2862.

Research output: Contribution to journalArticle

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AU - Burrows, A D

AU - Green, M

AU - Lynam, J M

AU - Mahon, M F

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AB - The tripalladium cluster [Pd-3( mu(3)-CO)( mu-dppm)(3)](PF6)(2) (1) reacts with two equivalents of (BuCP)-Bu-t to give [Pd-3(mu-dppm)(3)(eta(1)-PCBut)(2)](PF6)(2) (2). Prolonged storage of acetone solutions of 2 only resulted in the isolation of [Pd-3(mu-dppm)(3)(eta(1):mu(3)-PCH2But)(OCMC2)](PF6)(2) (3). Compound 3 has been characterized by X-ray crystallography. (c) 2006 Elsevier B.V. All rights reserved.

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