Transannular, decarboxylative Claisen rearrangement reactions for the synthesis of sulfur-substituted vinylcyclopropanes

D Craig; S J Gore; M I Lansdell; Simon Lewis; A V W Mayweg; A J P White

doi:10.1039/c0cc00976h

Transannular, decarboxylative Claisen rearrangement reactions for the synthesis of sulfur-substituted vinylcyclopropanes

D Craig, S J Gore, M I Lansdell, Simon Lewis, A V W Mayweg, A J P White

Department of Chemistry

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Abstract

Unsaturated epsilon-lactones bearing an alpha-arylsulfonyl or alpha-arylsulfoximinyl substituent undergo stereoselective transannular, decarboxylative Claisen rearrangement to give substituted vinylcyclopropanes.

Original language	English
Pages (from-to)	4991-4993
Number of pages	3
Journal	Chemical Communications
Volume	46
Issue number	27
DOIs	https://doi.org/10.1039/c0cc00976h
Publication status	Published - 21 Jul 2010

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title = "Transannular, decarboxylative Claisen rearrangement reactions for the synthesis of sulfur-substituted vinylcyclopropanes",

abstract = "Unsaturated epsilon-lactones bearing an alpha-arylsulfonyl or alpha-arylsulfoximinyl substituent undergo stereoselective transannular, decarboxylative Claisen rearrangement to give substituted vinylcyclopropanes.",

author = "D Craig and Gore, {S J} and Lansdell, {M I} and Simon Lewis and Mayweg, {A V W} and White, {A J P}",

year = "2010",

month = jul,

day = "21",

doi = "10.1039/c0cc00976h",

language = "English",

volume = "46",

pages = "4991--4993",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Transannular, decarboxylative Claisen rearrangement reactions for the synthesis of sulfur-substituted vinylcyclopropanes

AU - Craig, D

AU - Gore, S J

AU - Lansdell, M I

AU - Lewis, Simon

AU - Mayweg, A V W

AU - White, A J P

PY - 2010/7/21

Y1 - 2010/7/21

N2 - Unsaturated epsilon-lactones bearing an alpha-arylsulfonyl or alpha-arylsulfoximinyl substituent undergo stereoselective transannular, decarboxylative Claisen rearrangement to give substituted vinylcyclopropanes.

AB - Unsaturated epsilon-lactones bearing an alpha-arylsulfonyl or alpha-arylsulfoximinyl substituent undergo stereoselective transannular, decarboxylative Claisen rearrangement to give substituted vinylcyclopropanes.

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UR - http://dx.doi.org/10.1039/c0cc00976h

U2 - 10.1039/c0cc00976h

DO - 10.1039/c0cc00976h

M3 - Article

SN - 1359-7345

VL - 46

SP - 4991

EP - 4993

JO - Chemical Communications

JF - Chemical Communications

IS - 27

ER -

Transannular, decarboxylative Claisen rearrangement reactions for the synthesis of sulfur-substituted vinylcyclopropanes

Abstract

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