trans-(mu-5,5 '-diethynyl-2,2 '-bipyridine)bis-[phenylbis(triethylphosphine)platinum(II)]

M S Khan; M K Al-Suti; B Ahrens; P R Raithby; S J Teat

doi:10.1107/s1600536804010359

trans-(mu-5,5 '-diethynyl-2,2 '-bipyridine)bis-[phenylbis(triethylphosphine)platinum(II)]

M S Khan, M K Al-Suti, B Ahrens, P R Raithby, S J Teat

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

3 Citations (SciVal)

Abstract

The title compound, [Pt-2(C6H5)(2)(C14H6N2)(C6H15P)(4)], is a dinuclear Pt-II di-yne complex that exhibits pi-conjugation along the molecular backbone. It is used as a model complex for rigid-rod platinum poly-yne polymers of which it is a precursor. Such compounds are of interest because of the extended pi-conjugation through the aromatic/heteroaromatic spacer group in the backbone. The asymmetric unit contains two half molecules of the title compound, each lying on a crystallographic centre of symmetry situated at the mid-point of the central C - C bond of the bipyridine unit.

Original language	English
Pages (from-to)	M735-M737
Journal	Acta Crystallographica Section E-Structure Reports Online
Volume	60
DOIs	https://doi.org/10.1107/s1600536804010359
Publication status	Published - 2004

Bibliographical note

ID number: ISI:000222371200014

Access to Document

10.1107/s1600536804010359

Cite this

@article{edf76d61785f4632bea64b97ee9bbf4b,

title = "trans-(mu-5,5 '-diethynyl-2,2 '-bipyridine)bis-[phenylbis(triethylphosphine)platinum(II)]",

abstract = "The title compound, [Pt-2(C6H5)(2)(C14H6N2)(C6H15P)(4)], is a dinuclear Pt-II di-yne complex that exhibits pi-conjugation along the molecular backbone. It is used as a model complex for rigid-rod platinum poly-yne polymers of which it is a precursor. Such compounds are of interest because of the extended pi-conjugation through the aromatic/heteroaromatic spacer group in the backbone. The asymmetric unit contains two half molecules of the title compound, each lying on a crystallographic centre of symmetry situated at the mid-point of the central C - C bond of the bipyridine unit.",

author = "Khan, {M S} and Al-Suti, {M K} and B Ahrens and Raithby, {P R} and Teat, {S J}",

note = "ID number: ISI:000222371200014",

year = "2004",

doi = "10.1107/s1600536804010359",

language = "English",

volume = "60",

pages = "M735--M737",

journal = "Acta Crystallographica Section E-Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

}

TY - JOUR

T1 - trans-(mu-5,5 '-diethynyl-2,2 '-bipyridine)bis-[phenylbis(triethylphosphine)platinum(II)]

AU - Khan, M S

AU - Al-Suti, M K

AU - Ahrens, B

AU - Raithby, P R

AU - Teat, S J

N1 - ID number: ISI:000222371200014

PY - 2004

Y1 - 2004

N2 - The title compound, [Pt-2(C6H5)(2)(C14H6N2)(C6H15P)(4)], is a dinuclear Pt-II di-yne complex that exhibits pi-conjugation along the molecular backbone. It is used as a model complex for rigid-rod platinum poly-yne polymers of which it is a precursor. Such compounds are of interest because of the extended pi-conjugation through the aromatic/heteroaromatic spacer group in the backbone. The asymmetric unit contains two half molecules of the title compound, each lying on a crystallographic centre of symmetry situated at the mid-point of the central C - C bond of the bipyridine unit.

AB - The title compound, [Pt-2(C6H5)(2)(C14H6N2)(C6H15P)(4)], is a dinuclear Pt-II di-yne complex that exhibits pi-conjugation along the molecular backbone. It is used as a model complex for rigid-rod platinum poly-yne polymers of which it is a precursor. Such compounds are of interest because of the extended pi-conjugation through the aromatic/heteroaromatic spacer group in the backbone. The asymmetric unit contains two half molecules of the title compound, each lying on a crystallographic centre of symmetry situated at the mid-point of the central C - C bond of the bipyridine unit.

U2 - 10.1107/s1600536804010359

DO - 10.1107/s1600536804010359

M3 - Article

SN - 1600-5368

VL - 60

SP - M735-M737

JO - Acta Crystallographica Section E-Structure Reports Online

JF - Acta Crystallographica Section E-Structure Reports Online

ER -

trans-(mu-5,5 '-diethynyl-2,2 '-bipyridine)bis-[phenylbis(triethylphosphine)platinum(II)]

Abstract

Bibliographical note

Access to Document

Fingerprint

Cite this