trans-mu-(2,5-dioctyl-1,4-phenylene)diethynylbis[phenylbis(triethylphosp hine)platinum(II)]

M S Khan; M K Al-Suti; M F Mahon; L Male; P R Raithby

doi:10.1107/s1600536803018889

trans-mu-(2,5-dioctyl-1,4-phenylene)diethynylbis[phenylbis(triethylphosp hine)platinum(II)]

M S Khan, M K Al-Suti, M F Mahon, L Male, P R Raithby

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

4 Citations (SciVal)

Abstract

The title compound, [Pt-2(C6H5)(2)(C26H36)(C6H15P)(4)], is a dinuclear Pt-II di-yne compound exhibiting pi-conjugation along the molecular backbone. It is used as a model species for rigid-rod platinum poly-yne compounds of which it is a precursor. Such compounds are of interest due to the extended pi-conjugation through the aromatic linker unit in the backbone. In this structure, the molecule lies on an inversion centre such that the asymmetric unit comprises half the formula unit.

Original language	English
Pages (from-to)	M833-M835
Journal	Acta Crystallographica Section E-Structure Reports Online
Volume	59
DOIs	https://doi.org/10.1107/s1600536803018889
Publication status	Published - 2003

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ID number: ISI:000185644100004

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title = "trans-mu-(2,5-dioctyl-1,4-phenylene)diethynylbis[phenylbis(triethylphosp hine)platinum(II)]",

abstract = "The title compound, [Pt-2(C6H5)(2)(C26H36)(C6H15P)(4)], is a dinuclear Pt-II di-yne compound exhibiting pi-conjugation along the molecular backbone. It is used as a model species for rigid-rod platinum poly-yne compounds of which it is a precursor. Such compounds are of interest due to the extended pi-conjugation through the aromatic linker unit in the backbone. In this structure, the molecule lies on an inversion centre such that the asymmetric unit comprises half the formula unit.",

author = "Khan, {M S} and Al-Suti, {M K} and Mahon, {M F} and L Male and Raithby, {P R}",

note = "ID number: ISI:000185644100004",

year = "2003",

doi = "10.1107/s1600536803018889",

language = "English",

volume = "59",

pages = "M833--M835",

journal = "Acta Crystallographica Section E-Structure Reports Online",

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publisher = "International Union of Crystallography",

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TY - JOUR

T1 - trans-mu-(2,5-dioctyl-1,4-phenylene)diethynylbis[phenylbis(triethylphosp hine)platinum(II)]

AU - Khan, M S

AU - Al-Suti, M K

AU - Mahon, M F

AU - Male, L

AU - Raithby, P R

N1 - ID number: ISI:000185644100004

PY - 2003

Y1 - 2003

N2 - The title compound, [Pt-2(C6H5)(2)(C26H36)(C6H15P)(4)], is a dinuclear Pt-II di-yne compound exhibiting pi-conjugation along the molecular backbone. It is used as a model species for rigid-rod platinum poly-yne compounds of which it is a precursor. Such compounds are of interest due to the extended pi-conjugation through the aromatic linker unit in the backbone. In this structure, the molecule lies on an inversion centre such that the asymmetric unit comprises half the formula unit.

AB - The title compound, [Pt-2(C6H5)(2)(C26H36)(C6H15P)(4)], is a dinuclear Pt-II di-yne compound exhibiting pi-conjugation along the molecular backbone. It is used as a model species for rigid-rod platinum poly-yne compounds of which it is a precursor. Such compounds are of interest due to the extended pi-conjugation through the aromatic linker unit in the backbone. In this structure, the molecule lies on an inversion centre such that the asymmetric unit comprises half the formula unit.

U2 - 10.1107/s1600536803018889

DO - 10.1107/s1600536803018889

M3 - Article

SN - 1600-5368

VL - 59

SP - M833-M835

JO - Acta Crystallographica Section E-Structure Reports Online

JF - Acta Crystallographica Section E-Structure Reports Online

ER -

trans-mu-(2,5-dioctyl-1,4-phenylene)diethynylbis[phenylbis(triethylphosp hine)platinum(II)]

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