trans-bis[(S)-(-)-2-aminomethyl-1-ethylpyrrolidine-kappa N-2]palladium(II) dichloride methanol trisolvate

M D Jones; F A A Paz; J E Davies; B F G Johnson; J Klinowski

doi:10.1107/s1600536803022943

trans-bis[(S)-(-)-2-aminomethyl-1-ethylpyrrolidine-kappa N-2]palladium(II) dichloride methanol trisolvate

M D Jones, F A A Paz, J E Davies, B F G Johnson, J Klinowski

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The crystal structure of the title compound, [Pd(C7H16N2)(2)]Cl-2.3CH(3)OH, has been determined at 180 (2) K in the non-centrosymmetric space group P2(1)2(1)2(1). The structure contains only one crystallographically unique Pd metal centre, showing a slightly distorted square-planar geometry, in which the two chiral (S)-(-)-2-aminomethyl-1-ethylpyrrolidine diamines are coordinated with a trans configuration in order to minimize the steric interaction between neighbouring substituent ethyl groups. [Pd(C7H16N2)(2)](2+) complex cations are strongly hydrogen-bonded to the Cl. anions and methanol molecules, forming supramolecular tapes running along the a axis.

Original language	English
Pages (from-to)	M1031-M1034
Journal	Acta Crystallographica Section E-Structure Reports Online
Volume	59
DOIs	https://doi.org/10.1107/s1600536803022943
Publication status	Published - 2003

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ID number: ISI:000186318900035

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title = "trans-bis[(S)-(-)-2-aminomethyl-1-ethylpyrrolidine-kappa N-2]palladium(II) dichloride methanol trisolvate",

abstract = "The crystal structure of the title compound, [Pd(C7H16N2)(2)]Cl-2.3CH(3)OH, has been determined at 180 (2) K in the non-centrosymmetric space group P2(1)2(1)2(1). The structure contains only one crystallographically unique Pd metal centre, showing a slightly distorted square-planar geometry, in which the two chiral (S)-(-)-2-aminomethyl-1-ethylpyrrolidine diamines are coordinated with a trans configuration in order to minimize the steric interaction between neighbouring substituent ethyl groups. [Pd(C7H16N2)(2)](2+) complex cations are strongly hydrogen-bonded to the Cl. anions and methanol molecules, forming supramolecular tapes running along the a axis.",

author = "Jones, \{M D\} and Paz, \{F A A\} and Davies, \{J E\} and Johnson, \{B F G\} and J Klinowski",

note = "ID number: ISI:000186318900035",

year = "2003",

doi = "10.1107/s1600536803022943",

language = "English",

volume = "59",

pages = "M1031--M1034",

journal = "Acta Crystallographica Section E-Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

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TY - JOUR

T1 - trans-bis[(S)-(-)-2-aminomethyl-1-ethylpyrrolidine-kappa N-2]palladium(II) dichloride methanol trisolvate

AU - Jones, M D

AU - Paz, F A A

AU - Davies, J E

AU - Johnson, B F G

AU - Klinowski, J

N1 - ID number: ISI:000186318900035

PY - 2003

Y1 - 2003

N2 - The crystal structure of the title compound, [Pd(C7H16N2)(2)]Cl-2.3CH(3)OH, has been determined at 180 (2) K in the non-centrosymmetric space group P2(1)2(1)2(1). The structure contains only one crystallographically unique Pd metal centre, showing a slightly distorted square-planar geometry, in which the two chiral (S)-(-)-2-aminomethyl-1-ethylpyrrolidine diamines are coordinated with a trans configuration in order to minimize the steric interaction between neighbouring substituent ethyl groups. [Pd(C7H16N2)(2)](2+) complex cations are strongly hydrogen-bonded to the Cl. anions and methanol molecules, forming supramolecular tapes running along the a axis.

AB - The crystal structure of the title compound, [Pd(C7H16N2)(2)]Cl-2.3CH(3)OH, has been determined at 180 (2) K in the non-centrosymmetric space group P2(1)2(1)2(1). The structure contains only one crystallographically unique Pd metal centre, showing a slightly distorted square-planar geometry, in which the two chiral (S)-(-)-2-aminomethyl-1-ethylpyrrolidine diamines are coordinated with a trans configuration in order to minimize the steric interaction between neighbouring substituent ethyl groups. [Pd(C7H16N2)(2)](2+) complex cations are strongly hydrogen-bonded to the Cl. anions and methanol molecules, forming supramolecular tapes running along the a axis.

U2 - 10.1107/s1600536803022943

DO - 10.1107/s1600536803022943

M3 - Article

SN - 1600-5368

VL - 59

SP - M1031-M1034

JO - Acta Crystallographica Section E-Structure Reports Online

JF - Acta Crystallographica Section E-Structure Reports Online

ER -

trans-bis[(S)-(-)-2-aminomethyl-1-ethylpyrrolidine-kappa N-2]palladium(II) dichloride methanol trisolvate

Abstract

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