trans-bis[(S)-(-)-2-aminomethyl-1-ethylpyrrolidine-kappa N-2]palladium(II) dichloride methanol trisolvate

M D Jones, F A A Paz, J E Davies, B F G Johnson, J Klinowski

Research output: Contribution to journalArticle

Abstract

The crystal structure of the title compound, [Pd(C7H16N2)(2)]Cl-2.3CH(3)OH, has been determined at 180 (2) K in the non-centrosymmetric space group P2(1)2(1)2(1). The structure contains only one crystallographically unique Pd metal centre, showing a slightly distorted square-planar geometry, in which the two chiral (S)-(-)-2-aminomethyl-1-ethylpyrrolidine diamines are coordinated with a trans configuration in order to minimize the steric interaction between neighbouring substituent ethyl groups. [Pd(C7H16N2)(2)](2+) complex cations are strongly hydrogen-bonded to the Cl. anions and methanol molecules, forming supramolecular tapes running along the a axis.
Original languageEnglish
Pages (from-to)M1031-M1034
JournalActa Crystallographica Section E-Structure Reports Online
Volume59
DOIs
Publication statusPublished - 2003

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Diamines
dichlorides
Palladium
Tapes
Anions
Methanol
Cations
palladium
Hydrogen
Negative ions
methyl alcohol
Crystal structure
Positive ions
Metals
Molecules
Geometry
diamines
tapes
anions
cations

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trans-bis[(S)-(-)-2-aminomethyl-1-ethylpyrrolidine-kappa N-2]palladium(II) dichloride methanol trisolvate. / Jones, M D; Paz, F A A; Davies, J E; Johnson, B F G; Klinowski, J.

In: Acta Crystallographica Section E-Structure Reports Online, Vol. 59, 2003, p. M1031-M1034.

Research output: Contribution to journalArticle

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title = "trans-bis[(S)-(-)-2-aminomethyl-1-ethylpyrrolidine-kappa N-2]palladium(II) dichloride methanol trisolvate",
abstract = "The crystal structure of the title compound, [Pd(C7H16N2)(2)]Cl-2.3CH(3)OH, has been determined at 180 (2) K in the non-centrosymmetric space group P2(1)2(1)2(1). The structure contains only one crystallographically unique Pd metal centre, showing a slightly distorted square-planar geometry, in which the two chiral (S)-(-)-2-aminomethyl-1-ethylpyrrolidine diamines are coordinated with a trans configuration in order to minimize the steric interaction between neighbouring substituent ethyl groups. [Pd(C7H16N2)(2)](2+) complex cations are strongly hydrogen-bonded to the Cl. anions and methanol molecules, forming supramolecular tapes running along the a axis.",
author = "Jones, {M D} and Paz, {F A A} and Davies, {J E} and Johnson, {B F G} and J Klinowski",
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T1 - trans-bis[(S)-(-)-2-aminomethyl-1-ethylpyrrolidine-kappa N-2]palladium(II) dichloride methanol trisolvate

AU - Jones, M D

AU - Paz, F A A

AU - Davies, J E

AU - Johnson, B F G

AU - Klinowski, J

N1 - ID number: ISI:000186318900035

PY - 2003

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N2 - The crystal structure of the title compound, [Pd(C7H16N2)(2)]Cl-2.3CH(3)OH, has been determined at 180 (2) K in the non-centrosymmetric space group P2(1)2(1)2(1). The structure contains only one crystallographically unique Pd metal centre, showing a slightly distorted square-planar geometry, in which the two chiral (S)-(-)-2-aminomethyl-1-ethylpyrrolidine diamines are coordinated with a trans configuration in order to minimize the steric interaction between neighbouring substituent ethyl groups. [Pd(C7H16N2)(2)](2+) complex cations are strongly hydrogen-bonded to the Cl. anions and methanol molecules, forming supramolecular tapes running along the a axis.

AB - The crystal structure of the title compound, [Pd(C7H16N2)(2)]Cl-2.3CH(3)OH, has been determined at 180 (2) K in the non-centrosymmetric space group P2(1)2(1)2(1). The structure contains only one crystallographically unique Pd metal centre, showing a slightly distorted square-planar geometry, in which the two chiral (S)-(-)-2-aminomethyl-1-ethylpyrrolidine diamines are coordinated with a trans configuration in order to minimize the steric interaction between neighbouring substituent ethyl groups. [Pd(C7H16N2)(2)](2+) complex cations are strongly hydrogen-bonded to the Cl. anions and methanol molecules, forming supramolecular tapes running along the a axis.

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DO - 10.1107/s1600536803022943

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SP - M1031-M1034

JO - Acta Crystallographica Section E-Structure Reports Online

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