Towards a novel hybrid hydrogen storage system featuring a PIM-1/MIL-101 adsorbent composite

Leighton Holyfield, Nick Weatherby, Andrew Burrows, Timothy Mays

Research output: Contribution to conferenceAbstract

Abstract

Hydrogen has long been touted as a replacement energy vector for fossil fuels in transport applications, as it boasts a number of benefits: it is abundant; relatively easy to produce; has the highest gravimetric energy density of any known chemical fuel; and is a ‘zero carbon’ fuel as it only produces water upon full combustion. However, hydrogen is a very sparse gas under standard conditions, and as such has a very low volumetric energy density. Therefore, one of the great issues to overcome in creating a ‘hydrogen economy’ is how to store this elemental fuel. The current industrial standard is compress the gas to 70 MPa in type III or type IV carbon fibre composite tanks. However, this method requires high strength, low density materials to be suitable for safe automotive applications, which are expensive. One alternative method for densifying hydrogen is the use of physisorption, in which the gas molecules interact with the surfaces of high surface area materials, allowing similar density rises but at lower pressures. This study is focussed on synthesising, characterising and modelling a novel adsorbent composite made from the polymer of intrinsic porosity PIM-1 and the metal organic framework MIL-101, around which a conceptual hydrogen tank will be designed. PIM-1 is a very interesting adsorbent as it is a fully soluble in polar aprotic solvents and can therefore be cast into films, without losing much of its porosity. This is due to its kinked and rigid molecular chains, which are incapable of relaxing fully and therefore maintain free volume within the material [1]. PIM-1 typically shows BET surface areas of ~ 800 m2 g-1, and a hydrogen uptake of 1.45 wt% at 77 K and 10 bar [2], which are low values and require improvement for use in an effective storage system. This study looks to perform this by embedding MIL-101 in a mixed matrix membrane-style film. MIL-101 is a popular and well-studied MOF, offering surface areas in excess of 3000 m2 g-1 and hydrogen uptakes as high as 6 wt% at 77 K and 8 MPa [3]. It is also thermally and hydrolytically stable. This study presents the synthesis of both materials and a number of composites of the two in varying quantities. These materials are then characterised for their adsorptive (N2, CO2, H2 isotherms) and thermal (TG-MS, DSC) properties, and the hydrogen adsorption behaviour modelled in preparation for a conceptual design. The relationship between composite composition and these properties will also be presented in a rule-of-mixtures style analysis. References: [1] Budd PM, Elabas ES, Ghanem BS, et al. Solution-Processed, Organophilic Membrane Derived from a Polymer of Intrinsic Microporosity. Adv Mater., 2004, 16, 456–459. [2] McKeown NB, Budd PM & Book D. Microporous Polymers as Potential Hydrogen Storage Materials, Macromol. Rapid Commun. 2007, 28, 995–1002 [3] Latroche M, Surblé S, Serre C et al. Hydrogen Storage in the Giant-Pore Metal-Organic Frameworks MIL-100 and MIL-101, Angew. Chem. Int. Ed. 2006, 45, 8227–8231
Original languageEnglish
Publication statusUnpublished - 13 Dec 2016
EventH2FC: Hydrogen & Fuel Cell SUPERGEN Researcher Conference - University of Ulster, Jordanstown Campus, Belfast, UK United Kingdom
Duration: 12 Dec 201614 Dec 2016
http://www.h2fcsupergen.com/conference/

Conference

ConferenceH2FC: Hydrogen & Fuel Cell SUPERGEN Researcher Conference
Abbreviated titleH2FC SUPERGEN Conference
CountryUK United Kingdom
CityBelfast
Period12/12/1614/12/16
Internet address

Fingerprint

Hydrogen storage
Adsorbents
Hydrogen
Composite materials
Polymers
Gases
Porosity
Metals
Membranes
Microporosity
Physisorption
MIL-101
Free volume
Conceptual design
Fossil fuels
Isotherms
Carbon
Adsorption
Molecules
Water

Keywords

  • hydrogen
  • storage
  • adsorption
  • PIM
  • MOF
  • composite

Cite this

Holyfield, L., Weatherby, N., Burrows, A., & Mays, T. (2016). Towards a novel hybrid hydrogen storage system featuring a PIM-1/MIL-101 adsorbent composite. Abstract from H2FC: Hydrogen & Fuel Cell SUPERGEN Researcher Conference, Belfast, UK United Kingdom.

Towards a novel hybrid hydrogen storage system featuring a PIM-1/MIL-101 adsorbent composite. / Holyfield, Leighton; Weatherby, Nick; Burrows, Andrew; Mays, Timothy.

2016. Abstract from H2FC: Hydrogen & Fuel Cell SUPERGEN Researcher Conference, Belfast, UK United Kingdom.

Research output: Contribution to conferenceAbstract

Holyfield, L, Weatherby, N, Burrows, A & Mays, T 2016, 'Towards a novel hybrid hydrogen storage system featuring a PIM-1/MIL-101 adsorbent composite' H2FC: Hydrogen & Fuel Cell SUPERGEN Researcher Conference, Belfast, UK United Kingdom, 12/12/16 - 14/12/16, .
Holyfield L, Weatherby N, Burrows A, Mays T. Towards a novel hybrid hydrogen storage system featuring a PIM-1/MIL-101 adsorbent composite. 2016. Abstract from H2FC: Hydrogen & Fuel Cell SUPERGEN Researcher Conference, Belfast, UK United Kingdom.
Holyfield, Leighton ; Weatherby, Nick ; Burrows, Andrew ; Mays, Timothy. / Towards a novel hybrid hydrogen storage system featuring a PIM-1/MIL-101 adsorbent composite. Abstract from H2FC: Hydrogen & Fuel Cell SUPERGEN Researcher Conference, Belfast, UK United Kingdom.
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AU - Burrows, Andrew

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N2 - Hydrogen has long been touted as a replacement energy vector for fossil fuels in transport applications, as it boasts a number of benefits: it is abundant; relatively easy to produce; has the highest gravimetric energy density of any known chemical fuel; and is a ‘zero carbon’ fuel as it only produces water upon full combustion. However, hydrogen is a very sparse gas under standard conditions, and as such has a very low volumetric energy density. Therefore, one of the great issues to overcome in creating a ‘hydrogen economy’ is how to store this elemental fuel. The current industrial standard is compress the gas to 70 MPa in type III or type IV carbon fibre composite tanks. However, this method requires high strength, low density materials to be suitable for safe automotive applications, which are expensive. One alternative method for densifying hydrogen is the use of physisorption, in which the gas molecules interact with the surfaces of high surface area materials, allowing similar density rises but at lower pressures. This study is focussed on synthesising, characterising and modelling a novel adsorbent composite made from the polymer of intrinsic porosity PIM-1 and the metal organic framework MIL-101, around which a conceptual hydrogen tank will be designed. PIM-1 is a very interesting adsorbent as it is a fully soluble in polar aprotic solvents and can therefore be cast into films, without losing much of its porosity. This is due to its kinked and rigid molecular chains, which are incapable of relaxing fully and therefore maintain free volume within the material [1]. PIM-1 typically shows BET surface areas of ~ 800 m2 g-1, and a hydrogen uptake of 1.45 wt% at 77 K and 10 bar [2], which are low values and require improvement for use in an effective storage system. This study looks to perform this by embedding MIL-101 in a mixed matrix membrane-style film. MIL-101 is a popular and well-studied MOF, offering surface areas in excess of 3000 m2 g-1 and hydrogen uptakes as high as 6 wt% at 77 K and 8 MPa [3]. It is also thermally and hydrolytically stable. This study presents the synthesis of both materials and a number of composites of the two in varying quantities. These materials are then characterised for their adsorptive (N2, CO2, H2 isotherms) and thermal (TG-MS, DSC) properties, and the hydrogen adsorption behaviour modelled in preparation for a conceptual design. The relationship between composite composition and these properties will also be presented in a rule-of-mixtures style analysis. References: [1] Budd PM, Elabas ES, Ghanem BS, et al. Solution-Processed, Organophilic Membrane Derived from a Polymer of Intrinsic Microporosity. Adv Mater., 2004, 16, 456–459. [2] McKeown NB, Budd PM & Book D. Microporous Polymers as Potential Hydrogen Storage Materials, Macromol. Rapid Commun. 2007, 28, 995–1002 [3] Latroche M, Surblé S, Serre C et al. Hydrogen Storage in the Giant-Pore Metal-Organic Frameworks MIL-100 and MIL-101, Angew. Chem. Int. Ed. 2006, 45, 8227–8231

AB - Hydrogen has long been touted as a replacement energy vector for fossil fuels in transport applications, as it boasts a number of benefits: it is abundant; relatively easy to produce; has the highest gravimetric energy density of any known chemical fuel; and is a ‘zero carbon’ fuel as it only produces water upon full combustion. However, hydrogen is a very sparse gas under standard conditions, and as such has a very low volumetric energy density. Therefore, one of the great issues to overcome in creating a ‘hydrogen economy’ is how to store this elemental fuel. The current industrial standard is compress the gas to 70 MPa in type III or type IV carbon fibre composite tanks. However, this method requires high strength, low density materials to be suitable for safe automotive applications, which are expensive. One alternative method for densifying hydrogen is the use of physisorption, in which the gas molecules interact with the surfaces of high surface area materials, allowing similar density rises but at lower pressures. This study is focussed on synthesising, characterising and modelling a novel adsorbent composite made from the polymer of intrinsic porosity PIM-1 and the metal organic framework MIL-101, around which a conceptual hydrogen tank will be designed. PIM-1 is a very interesting adsorbent as it is a fully soluble in polar aprotic solvents and can therefore be cast into films, without losing much of its porosity. This is due to its kinked and rigid molecular chains, which are incapable of relaxing fully and therefore maintain free volume within the material [1]. PIM-1 typically shows BET surface areas of ~ 800 m2 g-1, and a hydrogen uptake of 1.45 wt% at 77 K and 10 bar [2], which are low values and require improvement for use in an effective storage system. This study looks to perform this by embedding MIL-101 in a mixed matrix membrane-style film. MIL-101 is a popular and well-studied MOF, offering surface areas in excess of 3000 m2 g-1 and hydrogen uptakes as high as 6 wt% at 77 K and 8 MPa [3]. It is also thermally and hydrolytically stable. This study presents the synthesis of both materials and a number of composites of the two in varying quantities. These materials are then characterised for their adsorptive (N2, CO2, H2 isotherms) and thermal (TG-MS, DSC) properties, and the hydrogen adsorption behaviour modelled in preparation for a conceptual design. The relationship between composite composition and these properties will also be presented in a rule-of-mixtures style analysis. References: [1] Budd PM, Elabas ES, Ghanem BS, et al. Solution-Processed, Organophilic Membrane Derived from a Polymer of Intrinsic Microporosity. Adv Mater., 2004, 16, 456–459. [2] McKeown NB, Budd PM & Book D. Microporous Polymers as Potential Hydrogen Storage Materials, Macromol. Rapid Commun. 2007, 28, 995–1002 [3] Latroche M, Surblé S, Serre C et al. Hydrogen Storage in the Giant-Pore Metal-Organic Frameworks MIL-100 and MIL-101, Angew. Chem. Int. Ed. 2006, 45, 8227–8231

KW - hydrogen

KW - storage

KW - adsorption

KW - PIM

KW - MOF

KW - composite

M3 - Abstract

ER -