Tin(H) aminoalkoxides and heterobimetallic derivatives: the structures of Sn-6(O)(4)(dmae)(4), Sn-6(O)(4)(OEt)(4) and [Sn(dmae)(2)Cd(acac)(2)](2)

N Hollingsworth; G A Horley; M Mazhar; M F Mahon; K C Molloy; P W Haycock; C P Myers; G W Critchlow

doi:10.1002/aoc.1118

Tin(H) aminoalkoxides and heterobimetallic derivatives: the structures of Sn-6(O)(4)(dmae)(4), Sn-6(O)(4)(OEt)(4) and [Sn(dmae)(2)Cd(acac)(2)](2)

N Hollingsworth, G A Horley, M Mazhar, M F Mahon, K C Molloy, P W Haycock, C P Myers, G W Critchlow

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

25 Citations (SciVal)

Abstract

Tin(II) methoxide reacts with N,N'-dimethylaminoethanol (dmaeH) to yield Sn(dmae)(2) (1) along with small amounts of the hydrolysis product Sn-6(O)(4)(dmae)(4) (2). The geometrically more regular iso-structural cage Sn-6(O)(4)(OEt)(4) (3) was obtained as the only tractable product isolated from reaction of 2 and Sb(OEt)(3), while 1 reacted with CdX2 (X = acac, I) to afford Sn(dmae)(2)Cd(acac)(2) (4) and Sn(dmae)(2)CdI2 (5). The X-ray structures of 2, 3 and 4 are reported. Decomposition of 4 under aerosol-assisted chemical vapour deposition conditions leads to amorphous tin oxide films with no detectable cadmium (i.e. ca < 2% cadmium), rather than a stoichiometric Sn:Cd oxide. Copyright (c) 2006 John Wiley & Sons, Ltd.

Original language	English
Pages (from-to)	687-695
Number of pages	9
Journal	Applied Organometallic Chemistry
Volume	20
Issue number	10
DOIs	https://doi.org/10.1002/aoc.1118
Publication status	Published - 2006

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ID number: ISI:000241127400014

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@article{b37de6f2b3084c1e83cfe7d3b77c09b7,

title = "Tin(H) aminoalkoxides and heterobimetallic derivatives: the structures of Sn-6(O)(4)(dmae)(4), Sn-6(O)(4)(OEt)(4) and [Sn(dmae)(2)Cd(acac)(2)](2)",

abstract = "Tin(II) methoxide reacts with N,N'-dimethylaminoethanol (dmaeH) to yield Sn(dmae)(2) (1) along with small amounts of the hydrolysis product Sn-6(O)(4)(dmae)(4) (2). The geometrically more regular iso-structural cage Sn-6(O)(4)(OEt)(4) (3) was obtained as the only tractable product isolated from reaction of 2 and Sb(OEt)(3), while 1 reacted with CdX2 (X = acac, I) to afford Sn(dmae)(2)Cd(acac)(2) (4) and Sn(dmae)(2)CdI2 (5). The X-ray structures of 2, 3 and 4 are reported. Decomposition of 4 under aerosol-assisted chemical vapour deposition conditions leads to amorphous tin oxide films with no detectable cadmium (i.e. ca < 2% cadmium), rather than a stoichiometric Sn:Cd oxide. Copyright (c) 2006 John Wiley & Sons, Ltd.",

author = "N Hollingsworth and Horley, {G A} and M Mazhar and Mahon, {M F} and Molloy, {K C} and Haycock, {P W} and Myers, {C P} and Critchlow, {G W}",

note = "ID number: ISI:000241127400014",

year = "2006",

doi = "10.1002/aoc.1118",

language = "English",

volume = "20",

pages = "687--695",

journal = "Applied Organometallic Chemistry",

issn = "0268-2605",

publisher = "John Wiley and Sons Inc.",

number = "10",

}

TY - JOUR

T1 - Tin(H) aminoalkoxides and heterobimetallic derivatives: the structures of Sn-6(O)(4)(dmae)(4), Sn-6(O)(4)(OEt)(4) and [Sn(dmae)(2)Cd(acac)(2)](2)

AU - Hollingsworth, N

AU - Horley, G A

AU - Mazhar, M

AU - Mahon, M F

AU - Molloy, K C

AU - Haycock, P W

AU - Myers, C P

AU - Critchlow, G W

N1 - ID number: ISI:000241127400014

PY - 2006

Y1 - 2006

N2 - Tin(II) methoxide reacts with N,N'-dimethylaminoethanol (dmaeH) to yield Sn(dmae)(2) (1) along with small amounts of the hydrolysis product Sn-6(O)(4)(dmae)(4) (2). The geometrically more regular iso-structural cage Sn-6(O)(4)(OEt)(4) (3) was obtained as the only tractable product isolated from reaction of 2 and Sb(OEt)(3), while 1 reacted with CdX2 (X = acac, I) to afford Sn(dmae)(2)Cd(acac)(2) (4) and Sn(dmae)(2)CdI2 (5). The X-ray structures of 2, 3 and 4 are reported. Decomposition of 4 under aerosol-assisted chemical vapour deposition conditions leads to amorphous tin oxide films with no detectable cadmium (i.e. ca < 2% cadmium), rather than a stoichiometric Sn:Cd oxide. Copyright (c) 2006 John Wiley & Sons, Ltd.

AB - Tin(II) methoxide reacts with N,N'-dimethylaminoethanol (dmaeH) to yield Sn(dmae)(2) (1) along with small amounts of the hydrolysis product Sn-6(O)(4)(dmae)(4) (2). The geometrically more regular iso-structural cage Sn-6(O)(4)(OEt)(4) (3) was obtained as the only tractable product isolated from reaction of 2 and Sb(OEt)(3), while 1 reacted with CdX2 (X = acac, I) to afford Sn(dmae)(2)Cd(acac)(2) (4) and Sn(dmae)(2)CdI2 (5). The X-ray structures of 2, 3 and 4 are reported. Decomposition of 4 under aerosol-assisted chemical vapour deposition conditions leads to amorphous tin oxide films with no detectable cadmium (i.e. ca < 2% cadmium), rather than a stoichiometric Sn:Cd oxide. Copyright (c) 2006 John Wiley & Sons, Ltd.

U2 - 10.1002/aoc.1118

DO - 10.1002/aoc.1118

M3 - Article

SN - 0268-2605

VL - 20

SP - 687

EP - 695

JO - Applied Organometallic Chemistry

JF - Applied Organometallic Chemistry

IS - 10

ER -

Tin(H) aminoalkoxides and heterobimetallic derivatives: the structures of Sn-6(O)(4)(dmae)(4), Sn-6(O)(4)(OEt)(4) and [Sn(dmae)(2)Cd(acac)(2)](2)

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