THz-frequency modulation of the Hubbard U in an organic Mott insulator

R. Singla, G. Cotugno, S. Kaiser, M. Först, M. Mitrano, H. Y. Liu, A. Cartella, C. Manzoni, H. Okamoto, T. Hasegawa, S. R. Clark, D. Jaksch, A. Cavalleri

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Abstract

We use midinfrared pulses with stable carrier-envelope phase offset to drive molecular vibrations in the charge transfer salt ET-F2TCNQ, a prototypical one-dimensional Mott insulator. We find that the Mott gap, which is probed resonantly with 10 fs laser pulses, oscillates with the pump field. This observation reveals that molecular excitations can coherently perturb the electronic on-site interactions (Hubbard U) by changing the local orbital wave function. The gap oscillates at twice the frequency of the vibrational mode, indicating that the molecular distortions couple quadratically to the local charge density.

Original languageEnglish
Article number187401
Pages (from-to)1 - 6
Number of pages6
JournalPhysical Review Letters
Volume115
Issue number18
Early online date29 Oct 2015
DOIs
Publication statusPublished - 30 Oct 2015

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