TY - JOUR
T1 - Three-Dimensional Nanostructured Palladium with Single Diamond Architecture for Enhanced Catalytic Activity
AU - Burton, Matthew
AU - Selvam, Anand
AU - Lawrie-Ashton, Jake
AU - Squires, Adam
AU - Terrill, Nicholas
AU - Nandhakumar, Iris
PY - 2018/10/31
Y1 - 2018/10/31
N2 - Fuel cells are a key new green technology that have applications in both transport and portable power generation. Carbon-supported platinum (Pt) is used as an anode and cathode electrocatalyst in low-temperature fuel cells fueled with hydrogen or low-molecular-weight alcohols. The cost of Pt and the limited world supply are significant barriers to the widespread use of these types of fuel cells. Comparatively, palladium has a 3 times higher abundance in the Earth's crust. Here, a facile, low-temperature, and scalable synthetic route toward three-dimensional nanostructured palladium (Pd) employing electrochemical templating from inverse lyotropic lipid phases is presented. The obtained single diamond morphology Pd nanostructures exhibited excellent catalytic activity and stability toward methanol, ethanol, and glycerol oxidation compared to commercial Pd black, and the nanostructure was verified by small-angle X-ray scattering, scanning tunneling electron microscopy, and cyclic voltammetry.
AB - Fuel cells are a key new green technology that have applications in both transport and portable power generation. Carbon-supported platinum (Pt) is used as an anode and cathode electrocatalyst in low-temperature fuel cells fueled with hydrogen or low-molecular-weight alcohols. The cost of Pt and the limited world supply are significant barriers to the widespread use of these types of fuel cells. Comparatively, palladium has a 3 times higher abundance in the Earth's crust. Here, a facile, low-temperature, and scalable synthetic route toward three-dimensional nanostructured palladium (Pd) employing electrochemical templating from inverse lyotropic lipid phases is presented. The obtained single diamond morphology Pd nanostructures exhibited excellent catalytic activity and stability toward methanol, ethanol, and glycerol oxidation compared to commercial Pd black, and the nanostructure was verified by small-angle X-ray scattering, scanning tunneling electron microscopy, and cyclic voltammetry.
U2 - 10.1021/acsami.8b13230
DO - 10.1021/acsami.8b13230
M3 - Article
C2 - 30289235
SN - 1944-8244
VL - 10
SP - 37087
EP - 37094
JO - ACS Applied Materials and Interfaces
JF - ACS Applied Materials and Interfaces
IS - 43
ER -