Abstract
Secondary α-D and β-D6 equilibrium isotope effects are calculated by ab initio MO methods for gas-phase heterolyses of a range of 2-propyl substrates; an anomalous trend in the β-D6 effects with variation of the leaving group is accounted for by a model involving hyperconjugative and inductive contributions.
Original language | English |
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Pages (from-to) | 510-511 |
Number of pages | 2 |
Journal | Journal of the Chemical Society, Chemical Communications |
Issue number | 8 |
DOIs | |
Publication status | Published - 1 Jan 1985 |
ASJC Scopus subject areas
- Molecular Medicine