The X‐ray photoelectron spectra of Ir, IrO2 and IrCl3 revisited

S. J. Freakley; J Ruiz‐Esquius; D. J. Morgan

doi:10.1002/sia.6225

The X‐ray photoelectron spectra of Ir, IrO2 and IrCl3 revisited

S. J. Freakley, J Ruiz‐Esquius, D. J. Morgan

Cardiff University

Research output: Contribution to journal › Article › peer-review

269 Citations (SciVal)

574 Downloads (Pure)

Abstract

The X‐ray photoelectron spectra of metallic iridium and the technologically important iridium compounds, IrO₂ and IrCl₃, have been studied. The results not only improve the accuracy of published data but also expand the binding energy database of other iridium core‐levels. The difference between anhydrous and hydrated materials is explored, and the effect on curve‐fitting is discussed, together with the derivation of suitable line shapes for peak fitting of data acquired from a conventional monochromatic Al K_α X‐ray source.

Original language	English
Pages (from-to)	794-799
Number of pages	6
Journal	Surface and Interface Analysis
Volume	49
Issue number	8
Early online date	2 Mar 2017
DOIs	https://doi.org/10.1002/sia.6225
Publication status	Published - 31 Aug 2018

Access to Document

10.1002/sia.6225

The X-ray Photoelectron Spectra of Ir%2C IrO2 and IrCl3 Revisited (Resubmission)
This is the peer-reviewed version of the following article: Freakley, SJ, Ruiz‐Esquius, J & Morgan, DJ 2017, 'The X‐ray photoelectron spectra of Ir, IrO2 and IrCl3 revisited' Surface and Interface Analysis, vol. 49, no. 8, pp. 794-799 which has been published in final form at: https://doi.org/10.1002/sia.6225. this article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.
Accepted author manuscript, 755 KB

http://orca.cf.ac.uk/id/eprint/99099

Cite this

@article{ee5f62769f4d4b84aadd4b94faf1d01d,

title = "The X‐ray photoelectron spectra of Ir, IrO2 and IrCl3 revisited",

abstract = "The X‐ray photoelectron spectra of metallic iridium and the technologically important iridium compounds, IrO2 and IrCl3, have been studied. The results not only improve the accuracy of published data but also expand the binding energy database of other iridium core‐levels. The difference between anhydrous and hydrated materials is explored, and the effect on curve‐fitting is discussed, together with the derivation of suitable line shapes for peak fitting of data acquired from a conventional monochromatic Al Kα X‐ray source. ",

author = "Freakley, {S. J.} and J Ruiz‐Esquius and Morgan, {D. J.}",

year = "2018",

month = aug,

day = "31",

doi = "10.1002/sia.6225",

language = "English",

volume = "49",

pages = "794--799",

journal = "Surface and Interface Analysis",

issn = "0142-2421",

publisher = "John Wiley and Sons Inc.",

number = "8",

}

TY - JOUR

T1 - The X‐ray photoelectron spectra of Ir, IrO2 and IrCl3 revisited

AU - Freakley, S. J.

AU - Ruiz‐Esquius, J

AU - Morgan, D. J.

PY - 2018/8/31

Y1 - 2018/8/31

N2 - The X‐ray photoelectron spectra of metallic iridium and the technologically important iridium compounds, IrO2 and IrCl3, have been studied. The results not only improve the accuracy of published data but also expand the binding energy database of other iridium core‐levels. The difference between anhydrous and hydrated materials is explored, and the effect on curve‐fitting is discussed, together with the derivation of suitable line shapes for peak fitting of data acquired from a conventional monochromatic Al Kα X‐ray source.

AB - The X‐ray photoelectron spectra of metallic iridium and the technologically important iridium compounds, IrO2 and IrCl3, have been studied. The results not only improve the accuracy of published data but also expand the binding energy database of other iridium core‐levels. The difference between anhydrous and hydrated materials is explored, and the effect on curve‐fitting is discussed, together with the derivation of suitable line shapes for peak fitting of data acquired from a conventional monochromatic Al Kα X‐ray source.

U2 - 10.1002/sia.6225

DO - 10.1002/sia.6225

M3 - Article

SN - 0142-2421

VL - 49

SP - 794

EP - 799

JO - Surface and Interface Analysis

JF - Surface and Interface Analysis

IS - 8

ER -

The X‐ray photoelectron spectra of Ir, IrO2 and IrCl3 revisited

Abstract

Access to Document

Fingerprint

Cite this