The use of hexamethyldisilathiane for the synthesis of transition metal sulfides

C J Carmalt, C W Dinnage, I P Parkin, E S Peters, K Molloy, M A Colucci

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

The reaction of TiCl4 with hexamethyldisilathiane in diethyl ether at room temperature affords black precipitates which upon annealing under H2S at 800 degreesC results in the formation of crystalline TiS2. Similarly, reaction Of MCl5 (M = Nb, Ta, Mo) with S(SiMe3)(2) in diethyl ether at room temperature or toluene at reflux results in the initial formation of black precipitates MxSyClzSipCqHp. Annealing of these precipitates under static vacuum at 550 or at 800 degreesC under H2S affords MS2. The black precipitates and metal sulfides produced under all annealing conditions were analysed by powder X-ray diffraction, scanning electron microscopy, energy dispersive X-ray analysis and Raman spectroscopy. (C) 2003 Elsevier Science Ltd. All rights reserved.
Original languageEnglish
Pages (from-to)1255-1262
Number of pages8
JournalPolyhedron
Volume22
Issue number9
DOIs
Publication statusPublished - 2003

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Sulfides
Transition metals
sulfides
Precipitates
precipitates
transition metals
diethyl ether
Annealing
synthesis
Ether
annealing
Ethers
Energy dispersive X ray analysis
Toluene
room temperature
X ray powder diffraction
Raman spectroscopy
toluene
x rays
Metals

Cite this

Carmalt, C. J., Dinnage, C. W., Parkin, I. P., Peters, E. S., Molloy, K., & Colucci, M. A. (2003). The use of hexamethyldisilathiane for the synthesis of transition metal sulfides. Polyhedron, 22(9), 1255-1262. https://doi.org/10.1016/s0277-5387(03)00114-1

The use of hexamethyldisilathiane for the synthesis of transition metal sulfides. / Carmalt, C J; Dinnage, C W; Parkin, I P; Peters, E S; Molloy, K; Colucci, M A.

In: Polyhedron, Vol. 22, No. 9, 2003, p. 1255-1262.

Research output: Contribution to journalArticle

Carmalt, CJ, Dinnage, CW, Parkin, IP, Peters, ES, Molloy, K & Colucci, MA 2003, 'The use of hexamethyldisilathiane for the synthesis of transition metal sulfides', Polyhedron, vol. 22, no. 9, pp. 1255-1262. https://doi.org/10.1016/s0277-5387(03)00114-1
Carmalt CJ, Dinnage CW, Parkin IP, Peters ES, Molloy K, Colucci MA. The use of hexamethyldisilathiane for the synthesis of transition metal sulfides. Polyhedron. 2003;22(9):1255-1262. https://doi.org/10.1016/s0277-5387(03)00114-1
Carmalt, C J ; Dinnage, C W ; Parkin, I P ; Peters, E S ; Molloy, K ; Colucci, M A. / The use of hexamethyldisilathiane for the synthesis of transition metal sulfides. In: Polyhedron. 2003 ; Vol. 22, No. 9. pp. 1255-1262.
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