The use of five-coordinate aluminum alkyls to prepare molecules containing a single Al-O-Si linkage

David A. Atwood; Michael S. Hill; Jolin A. Jegier; Drew Rutherford

doi:10.1021/om9700831

The use of five-coordinate aluminum alkyls to prepare molecules containing a single Al-O-Si linkage

David A. Atwood, Michael S. Hill, Jolin A. Jegier, Drew Rutherford

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Abstract

The present work entails the synthesis and first structural characterization of complexes possessing a single Al-O-Si linkage. These are of the formula LAlOSiPh₃ (L = Salen(^tBu) (N,N′-ethylenebis(3, 5-di-tert-butylsalicylideneimine)) (11); Salpen(^tBu) N,N′-propylenebis(3,5-di-tert-butylsalicylideneimine)) (12); Salophen(^tBu) (N,N′-phenylenebis(3,5-di-tert-butylsalicylideneimine)) (13); and Salomphen(^tBu) (N,N′-(3,4-dimethylphenylene)bis(3,5-di-tert-butylsalicylideneimine)) (14). They are formed by combining the novel five-coordinate aluminum alkyl starting materials L(^tBu)AIR (where L = Salen(^tBu), R = Me (1), Et (2), ⁱBu (3); Salpen(^tBu), R = Me (4), Salophen(^tBu) R = Me (5), Et (6), ⁱBu (7); and Salomphen, R = Me (8), Et (9), ⁱBu (10)) with Ph₃SiOH in toluene. All of the compounds were characterized spectroscopically and, in the case of 1, 10, 11, 12, and 13, by X-ray crystallography.

Original language	English
Pages (from-to)	2659-2664
Number of pages	6
Journal	Organometallics
Volume	16
Issue number	12
DOIs	https://doi.org/10.1021/om9700831
Publication status	Published - 15 May 1997

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1021/om9700831

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Atwood, D. A., Hill, M. S., Jegier, J. A., & Rutherford, D. (1997). The use of five-coordinate aluminum alkyls to prepare molecules containing a single Al-O-Si linkage. Organometallics, 16(12), 2659-2664. https://doi.org/10.1021/om9700831

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title = "The use of five-coordinate aluminum alkyls to prepare molecules containing a single Al-O-Si linkage",

abstract = "The present work entails the synthesis and first structural characterization of complexes possessing a single Al-O-Si linkage. These are of the formula LAlOSiPh3 (L = Salen(tBu) (N,N′-ethylenebis(3, 5-di-tert-butylsalicylideneimine)) (11); Salpen(tBu) N,N′-propylenebis(3,5-di-tert-butylsalicylideneimine)) (12); Salophen(tBu) (N,N′-phenylenebis(3,5-di-tert-butylsalicylideneimine)) (13); and Salomphen(tBu) (N,N′-(3,4-dimethylphenylene)bis(3,5-di-tert-butylsalicylideneimine)) (14). They are formed by combining the novel five-coordinate aluminum alkyl starting materials L(tBu)AIR (where L = Salen(tBu), R = Me (1), Et (2), iBu (3); Salpen(tBu), R = Me (4), Salophen(tBu) R = Me (5), Et (6), iBu (7); and Salomphen, R = Me (8), Et (9), iBu (10)) with Ph3SiOH in toluene. All of the compounds were characterized spectroscopically and, in the case of 1, 10, 11, 12, and 13, by X-ray crystallography.",

author = "Atwood, {David A.} and Hill, {Michael S.} and Jegier, {Jolin A.} and Drew Rutherford",

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T1 - The use of five-coordinate aluminum alkyls to prepare molecules containing a single Al-O-Si linkage

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AU - Jegier, Jolin A.

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N2 - The present work entails the synthesis and first structural characterization of complexes possessing a single Al-O-Si linkage. These are of the formula LAlOSiPh3 (L = Salen(tBu) (N,N′-ethylenebis(3, 5-di-tert-butylsalicylideneimine)) (11); Salpen(tBu) N,N′-propylenebis(3,5-di-tert-butylsalicylideneimine)) (12); Salophen(tBu) (N,N′-phenylenebis(3,5-di-tert-butylsalicylideneimine)) (13); and Salomphen(tBu) (N,N′-(3,4-dimethylphenylene)bis(3,5-di-tert-butylsalicylideneimine)) (14). They are formed by combining the novel five-coordinate aluminum alkyl starting materials L(tBu)AIR (where L = Salen(tBu), R = Me (1), Et (2), iBu (3); Salpen(tBu), R = Me (4), Salophen(tBu) R = Me (5), Et (6), iBu (7); and Salomphen, R = Me (8), Et (9), iBu (10)) with Ph3SiOH in toluene. All of the compounds were characterized spectroscopically and, in the case of 1, 10, 11, 12, and 13, by X-ray crystallography.

AB - The present work entails the synthesis and first structural characterization of complexes possessing a single Al-O-Si linkage. These are of the formula LAlOSiPh3 (L = Salen(tBu) (N,N′-ethylenebis(3, 5-di-tert-butylsalicylideneimine)) (11); Salpen(tBu) N,N′-propylenebis(3,5-di-tert-butylsalicylideneimine)) (12); Salophen(tBu) (N,N′-phenylenebis(3,5-di-tert-butylsalicylideneimine)) (13); and Salomphen(tBu) (N,N′-(3,4-dimethylphenylene)bis(3,5-di-tert-butylsalicylideneimine)) (14). They are formed by combining the novel five-coordinate aluminum alkyl starting materials L(tBu)AIR (where L = Salen(tBu), R = Me (1), Et (2), iBu (3); Salpen(tBu), R = Me (4), Salophen(tBu) R = Me (5), Et (6), iBu (7); and Salomphen, R = Me (8), Et (9), iBu (10)) with Ph3SiOH in toluene. All of the compounds were characterized spectroscopically and, in the case of 1, 10, 11, 12, and 13, by X-ray crystallography.

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