The synthesis of the first hexaruthenium nitrosyl cluster species; X-ray analysis of Ru6C(CO)14(NO)2 and Ru6C(CO)15(NO)(AuPPh3)

Brian F.G. Johnson; Jack Lewis; William J.H. Nelson; Jose Puga; Paul R. Raithby; Dario Braga; Mary McPartlin; William Clegg

doi:10.1016/0022-328X(83)80232-0

The synthesis of the first hexaruthenium nitrosyl cluster species; X-ray analysis of Ru₆C(CO)₁₄(NO)₂ and Ru₆C(CO)₁₅(NO)(AuPPh₃)

Brian F.G. Johnson, Jack Lewis, William J.H. Nelson, Jose Puga, Paul R. Raithby, Dario Braga, Mary McPartlin, William Clegg

Research output: Contribution to journal › Article › peer-review

Abstract

Reaction of Ru₆C(CO)₁₇ with [(PH₃P₂N] [NO₂] has given the anion [Ru₆C(CO)₁₅(NO)]^- (I) which reacts with [NO]⁺ to give Ru₆C(CO)₁₄(NO)₂ (II) and with Ph₃PAuCl to give Ru₆C(CO)₁₅(NO)AuPPh3 (III); X-ray analysis of II and III confirms the presence of terminal NO-ligands as indicated by the IR spectra, and shows that the AuPPh₃ ligand in III adopts a μ₃-bonding mode.

Original language	English
Pages (from-to)	C13-C16
Journal	Journal of Organometallic Chemistry
Volume	243
Issue number	1
DOIs	https://doi.org/10.1016/0022-328X(83)80232-0
Publication status	Published - 1 Feb 1983

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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title = "The synthesis of the first hexaruthenium nitrosyl cluster species; X-ray analysis of Ru6C(CO)14(NO)2 and Ru6C(CO)15(NO)(AuPPh3)",

abstract = "Reaction of Ru6C(CO)17 with [(PH3P2N] [NO2] has given the anion [Ru6C(CO)15(NO)]- (I) which reacts with [NO]+ to give Ru6C(CO)14(NO)2 (II) and with Ph3PAuCl to give Ru6C(CO)15(NO)AuPPh3 (III); X-ray analysis of II and III confirms the presence of terminal NO-ligands as indicated by the IR spectra, and shows that the AuPPh3 ligand in III adopts a μ3-bonding mode.",

author = "Johnson, \{Brian F.G.\} and Jack Lewis and Nelson, \{William J.H.\} and Jose Puga and \{R. Raithby\}, Paul and Dario Braga and Mary McPartlin and William Clegg",

year = "1983",

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doi = "10.1016/0022-328X(83)80232-0",

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T1 - The synthesis of the first hexaruthenium nitrosyl cluster species; X-ray analysis of Ru6C(CO)14(NO)2 and Ru6C(CO)15(NO)(AuPPh3)

AU - Johnson, Brian F.G.

AU - Lewis, Jack

AU - Nelson, William J.H.

AU - Puga, Jose

AU - R. Raithby, Paul

AU - Braga, Dario

AU - McPartlin, Mary

AU - Clegg, William

PY - 1983/2/1

Y1 - 1983/2/1

N2 - Reaction of Ru6C(CO)17 with [(PH3P2N] [NO2] has given the anion [Ru6C(CO)15(NO)]- (I) which reacts with [NO]+ to give Ru6C(CO)14(NO)2 (II) and with Ph3PAuCl to give Ru6C(CO)15(NO)AuPPh3 (III); X-ray analysis of II and III confirms the presence of terminal NO-ligands as indicated by the IR spectra, and shows that the AuPPh3 ligand in III adopts a μ3-bonding mode.

AB - Reaction of Ru6C(CO)17 with [(PH3P2N] [NO2] has given the anion [Ru6C(CO)15(NO)]- (I) which reacts with [NO]+ to give Ru6C(CO)14(NO)2 (II) and with Ph3PAuCl to give Ru6C(CO)15(NO)AuPPh3 (III); X-ray analysis of II and III confirms the presence of terminal NO-ligands as indicated by the IR spectra, and shows that the AuPPh3 ligand in III adopts a μ3-bonding mode.

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U2 - 10.1016/0022-328X(83)80232-0

DO - 10.1016/0022-328X(83)80232-0

M3 - Article

AN - SCOPUS:4244168920

SN - 0022-328X

VL - 243

SP - C13-C16

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1

ER -

The synthesis of the first hexaruthenium nitrosyl cluster species; X-ray analysis of Ru₆C(CO)₁₄(NO)₂ and Ru₆C(CO)₁₅(NO)(AuPPh₃)

Abstract

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