The synthesis and crystal structure of the first metal-bound stannatrane complex Os(Sn[OCH2CH2]3N) (η2-S2CNMe2)(CO)(PPh3) 2: (See abstract)

Clifton E.F. Rickard; Warren R. Roper; Timothy J. Woodman; L. James Wright

doi:10.1039/a901408j

The synthesis and crystal structure of the first metal-bound stannatrane complex Os(Sn[OCH₂CH₂]₃N) (η²-S₂CNMe₂)(CO)(PPh₃) ₂: (See abstract)

Clifton E.F. Rickard, Warren R. Roper, Timothy J. Woodman, L. James Wright

Auckland University of Technology

Research output: Contribution to journal › Article › peer-review

45 Citations (SciVal)

Abstract

The first metal substituted stannatrane, Os(Sn[OCH₂CH₂]3N)(η²-S₂CNMe ₂)(CO)(PPh₃)₂, has been synthesised by reaction between triethanolamine and the triiodostannyl osmium complex Os(SnI₃)(η²-S₂CNMe₂)- (CO)(PPh₃)₂: the transannular Sn-N distance of 2.422(4) Å indicates a bonding interaction which is not seen in the corresponding silatranyl complex Os(Si[OCH₂CH₂]₃N)(η²-S ₂CNMe₂)(CO)(PPh₃)₂ which has an Si-N distance of 3.176(6) Å.

Original language	English
Pages (from-to)	837-838
Number of pages	2
Journal	Chemical Communications
Issue number	9
DOIs	https://doi.org/10.1039/a901408j
Publication status	Published - 7 May 1999

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "The synthesis and crystal structure of the first metal-bound stannatrane complex Os(Sn[OCH2CH2]3N) (η2-S2CNMe2)(CO)(PPh3) 2: (See abstract)",

abstract = "The first metal substituted stannatrane, Os(Sn[OCH2CH2]3N)(η2-S2CNMe 2)(CO)(PPh3)2, has been synthesised by reaction between triethanolamine and the triiodostannyl osmium complex Os(SnI3)(η2-S2CNMe2)- (CO)(PPh3)2: the transannular Sn-N distance of 2.422(4) {\AA} indicates a bonding interaction which is not seen in the corresponding silatranyl complex Os(Si[OCH2CH2]3N)(η2-S 2CNMe2)(CO)(PPh3)2 which has an Si-N distance of 3.176(6) {\AA}.",

author = "Rickard, {Clifton E.F.} and Roper, {Warren R.} and Woodman, {Timothy J.} and Wright, {L. James}",

year = "1999",

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language = "English",

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journal = "Chemical Communications",

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T1 - The synthesis and crystal structure of the first metal-bound stannatrane complex Os(Sn[OCH2CH2]3N) (η2-S2CNMe2)(CO)(PPh3) 2

T2 - (See abstract)

AU - Rickard, Clifton E.F.

AU - Roper, Warren R.

AU - Woodman, Timothy J.

AU - Wright, L. James

PY - 1999/5/7

Y1 - 1999/5/7

N2 - The first metal substituted stannatrane, Os(Sn[OCH2CH2]3N)(η2-S2CNMe 2)(CO)(PPh3)2, has been synthesised by reaction between triethanolamine and the triiodostannyl osmium complex Os(SnI3)(η2-S2CNMe2)- (CO)(PPh3)2: the transannular Sn-N distance of 2.422(4) Å indicates a bonding interaction which is not seen in the corresponding silatranyl complex Os(Si[OCH2CH2]3N)(η2-S 2CNMe2)(CO)(PPh3)2 which has an Si-N distance of 3.176(6) Å.

AB - The first metal substituted stannatrane, Os(Sn[OCH2CH2]3N)(η2-S2CNMe 2)(CO)(PPh3)2, has been synthesised by reaction between triethanolamine and the triiodostannyl osmium complex Os(SnI3)(η2-S2CNMe2)- (CO)(PPh3)2: the transannular Sn-N distance of 2.422(4) Å indicates a bonding interaction which is not seen in the corresponding silatranyl complex Os(Si[OCH2CH2]3N)(η2-S 2CNMe2)(CO)(PPh3)2 which has an Si-N distance of 3.176(6) Å.

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The synthesis and crystal structure of the first metal-bound stannatrane complex Os(Sn[OCH₂CH₂]₃N) (η²-S₂CNMe₂)(CO)(PPh₃) ₂: (See abstract)

Abstract

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