The synthesis and characterisation of C-triorganometallated (metal = Sn, Si) bis-(thienyl)- and bis-(pyrazolyl)alkanes, including the crystal structure of [(Ph3Sn)C3N2](2)CH2

M S Hill, M F Mahon, J M G McGinley, K C Molloy

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Abstract

C-organostannyl- and organosilyl-derivatives of 2-(thien-2-ylmethyl)thiophene and 1-[(1H-pyrazol-1-yl)methyl]-1H-pyrazole have been synthesised and characterised spectroscopically. Lithiation and subsequent substitution by R3M takes place at the 5,5' positions for both bis-heterocycles, and this is confirmed by the X-ray structure of 1,1'-[5,5'-(Ph3Sn)C3N2](2)CH2. (C) 2001 Elsevier Science Ltd. All rights reserved.
Original languageEnglish
Pages (from-to)1995-2002
Number of pages8
JournalPolyhedron
Volume20
Issue number15-16
Publication statusPublished - 2001

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Thiophenes
Alkanes
Thiophene
thiophenes
Paraffins
alkanes
Substitution reactions
Crystal structure
Metals
substitutes
Derivatives
X rays
crystal structure
synthesis
metals
x rays
pyrazole

Cite this

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title = "The synthesis and characterisation of C-triorganometallated (metal = Sn, Si) bis-(thienyl)- and bis-(pyrazolyl)alkanes, including the crystal structure of [(Ph3Sn)C3N2](2)CH2",
abstract = "C-organostannyl- and organosilyl-derivatives of 2-(thien-2-ylmethyl)thiophene and 1-[(1H-pyrazol-1-yl)methyl]-1H-pyrazole have been synthesised and characterised spectroscopically. Lithiation and subsequent substitution by R3M takes place at the 5,5' positions for both bis-heterocycles, and this is confirmed by the X-ray structure of 1,1'-[5,5'-(Ph3Sn)C3N2](2)CH2. (C) 2001 Elsevier Science Ltd. All rights reserved.",
author = "Hill, {M S} and Mahon, {M F} and McGinley, {J M G} and Molloy, {K C}",
note = "ID number: ISI:000169986500030",
year = "2001",
language = "English",
volume = "20",
pages = "1995--2002",
journal = "Polyhedron",
issn = "0277-5387",
publisher = "Elsevier",
number = "15-16",

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TY - JOUR

T1 - The synthesis and characterisation of C-triorganometallated (metal = Sn, Si) bis-(thienyl)- and bis-(pyrazolyl)alkanes, including the crystal structure of [(Ph3Sn)C3N2](2)CH2

AU - Hill, M S

AU - Mahon, M F

AU - McGinley, J M G

AU - Molloy, K C

N1 - ID number: ISI:000169986500030

PY - 2001

Y1 - 2001

N2 - C-organostannyl- and organosilyl-derivatives of 2-(thien-2-ylmethyl)thiophene and 1-[(1H-pyrazol-1-yl)methyl]-1H-pyrazole have been synthesised and characterised spectroscopically. Lithiation and subsequent substitution by R3M takes place at the 5,5' positions for both bis-heterocycles, and this is confirmed by the X-ray structure of 1,1'-[5,5'-(Ph3Sn)C3N2](2)CH2. (C) 2001 Elsevier Science Ltd. All rights reserved.

AB - C-organostannyl- and organosilyl-derivatives of 2-(thien-2-ylmethyl)thiophene and 1-[(1H-pyrazol-1-yl)methyl]-1H-pyrazole have been synthesised and characterised spectroscopically. Lithiation and subsequent substitution by R3M takes place at the 5,5' positions for both bis-heterocycles, and this is confirmed by the X-ray structure of 1,1'-[5,5'-(Ph3Sn)C3N2](2)CH2. (C) 2001 Elsevier Science Ltd. All rights reserved.

M3 - Article

VL - 20

SP - 1995

EP - 2002

JO - Polyhedron

JF - Polyhedron

SN - 0277-5387

IS - 15-16

ER -