The synthesis and characterisation of C-triorganometallated (metal = Sn, Si) bis-(thienyl)- and bis-(pyrazolyl)alkanes, including the crystal structure of [(Ph3Sn)C3N2](2)CH2

M S Hill, M F Mahon, J M G McGinley, K C Molloy

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

C-organostannyl- and organosilyl-derivatives of 2-(thien-2-ylmethyl)thiophene and 1-[(1H-pyrazol-1-yl)methyl]-1H-pyrazole have been synthesised and characterised spectroscopically. Lithiation and subsequent substitution by R3M takes place at the 5,5' positions for both bis-heterocycles, and this is confirmed by the X-ray structure of 1,1'-[5,5'-(Ph3Sn)C3N2](2)CH2. (C) 2001 Elsevier Science Ltd. All rights reserved.
Original languageEnglish
Pages (from-to)1995-2002
Number of pages8
JournalPolyhedron
Volume20
Issue number15-16
Publication statusPublished - 2001

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