The synthesis and characterisation of C-triorganometallated (metal = Sn, Si) bis-(thienyl)- and bis-(pyrazolyl)alkanes, including the crystal structure of [(Ph3Sn)C3N2](2)CH2

M S Hill; M F Mahon; J M G McGinley; K C Molloy

The synthesis and characterisation of C-triorganometallated (metal = Sn, Si) bis-(thienyl)- and bis-(pyrazolyl)alkanes, including the crystal structure of [(Ph3Sn)C3N2](2)CH2

M S Hill, M F Mahon, J M G McGinley, K C Molloy

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

6 Citations (SciVal)

Abstract

C-organostannyl- and organosilyl-derivatives of 2-(thien-2-ylmethyl)thiophene and 1-[(1H-pyrazol-1-yl)methyl]-1H-pyrazole have been synthesised and characterised spectroscopically. Lithiation and subsequent substitution by R3M takes place at the 5,5' positions for both bis-heterocycles, and this is confirmed by the X-ray structure of 1,1'-[5,5'-(Ph3Sn)C3N2](2)CH2. (C) 2001 Elsevier Science Ltd. All rights reserved.

Original language	English
Pages (from-to)	1995-2002
Number of pages	8
Journal	Polyhedron
Volume	20
Issue number	15-16
Publication status	Published - 2001

Bibliographical note

ID number: ISI:000169986500030

Cite this

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title = "The synthesis and characterisation of C-triorganometallated (metal = Sn, Si) bis-(thienyl)- and bis-(pyrazolyl)alkanes, including the crystal structure of [(Ph3Sn)C3N2](2)CH2",

abstract = "C-organostannyl- and organosilyl-derivatives of 2-(thien-2-ylmethyl)thiophene and 1-[(1H-pyrazol-1-yl)methyl]-1H-pyrazole have been synthesised and characterised spectroscopically. Lithiation and subsequent substitution by R3M takes place at the 5,5' positions for both bis-heterocycles, and this is confirmed by the X-ray structure of 1,1'-[5,5'-(Ph3Sn)C3N2](2)CH2. (C) 2001 Elsevier Science Ltd. All rights reserved.",

author = "Hill, {M S} and Mahon, {M F} and McGinley, {J M G} and Molloy, {K C}",

note = "ID number: ISI:000169986500030",

year = "2001",

language = "English",

volume = "20",

pages = "1995--2002",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier",

number = "15-16",

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TY - JOUR

T1 - The synthesis and characterisation of C-triorganometallated (metal = Sn, Si) bis-(thienyl)- and bis-(pyrazolyl)alkanes, including the crystal structure of [(Ph3Sn)C3N2](2)CH2

AU - Hill, M S

AU - Mahon, M F

AU - McGinley, J M G

AU - Molloy, K C

N1 - ID number: ISI:000169986500030

PY - 2001

Y1 - 2001

N2 - C-organostannyl- and organosilyl-derivatives of 2-(thien-2-ylmethyl)thiophene and 1-[(1H-pyrazol-1-yl)methyl]-1H-pyrazole have been synthesised and characterised spectroscopically. Lithiation and subsequent substitution by R3M takes place at the 5,5' positions for both bis-heterocycles, and this is confirmed by the X-ray structure of 1,1'-[5,5'-(Ph3Sn)C3N2](2)CH2. (C) 2001 Elsevier Science Ltd. All rights reserved.

AB - C-organostannyl- and organosilyl-derivatives of 2-(thien-2-ylmethyl)thiophene and 1-[(1H-pyrazol-1-yl)methyl]-1H-pyrazole have been synthesised and characterised spectroscopically. Lithiation and subsequent substitution by R3M takes place at the 5,5' positions for both bis-heterocycles, and this is confirmed by the X-ray structure of 1,1'-[5,5'-(Ph3Sn)C3N2](2)CH2. (C) 2001 Elsevier Science Ltd. All rights reserved.

M3 - Article

SN - 0277-5387

VL - 20

SP - 1995

EP - 2002

JO - Polyhedron

JF - Polyhedron

IS - 15-16

ER -

The synthesis and characterisation of C-triorganometallated (metal = Sn, Si) bis-(thienyl)- and bis-(pyrazolyl)alkanes, including the crystal structure of [(Ph3Sn)C3N2](2)CH2

Abstract

Bibliographical note

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