The structures of strontium xanthates Sr(S2COR)2·xROH (R=Et, Pri, Bu t)

Y.V. Ebashi, S. Eggleston, Gabriele Kociok-Köhn, K.C. Molloy

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Abstract

The first structures of strontium xanthates Sr(S2COR)2(ROH)3·xROH [x=0, R=Et (1), iPr (2); x=1, R=tBu (3)] have been determined. All three species adopt an approximately pentagonal bipyramidal SrSO coordination sphere about the metal, although the lattice structures differ across the series and are determined by the hydrogen bonding network afforded via the alcohol moieties.

Original languageEnglish
Pages (from-to)85-89
Number of pages5
JournalMain Group Metal Chemistry
Volume37
Issue number3-4
Early online date12 Jun 2014
DOIs
Publication statusPublished - Jul 2014

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Ebashi, Y. V., Eggleston, S., Kociok-Köhn, G., & Molloy, K. C. (2014). The structures of strontium xanthates Sr(S2COR)2·xROH (R=Et, Pri, Bu t). Main Group Metal Chemistry, 37(3-4), 85-89. https://doi.org/10.1515/mgmc-2014-0008