The structure of 1,5-diazido-l,1,3,3,5,5-hexabutyltristannoxane

M. Hill, M. F. Mahon, K. C. Molloy

Research output: Contribution to journalArticlepeer-review

5 Citations (Scopus)

Abstract

The structure of the dimeric tristannoxane [(N3)Bu2Sn(Bu2SnO)2N3]2 has been characterised crystallographically and represents the first structurally authenticated tristannoxane without chelating ligands on every metal. The centrosymmetric dimer adopts a ladder structure in which each tin is five-coordinate. One azide bridges the two sides of the ladder in a 1, l-coordination mode while the other azide is monodentate. Crystal data: space group P-1 (no. 2), a = 9.401 (2), b = 13.651 (3), c = 14.821(5) Å α = 67.47(2), β = 73.96(2), γ = 86.76(2)°, Dcalc = 1.61 gcm-3, observed data = 3800, R = 0.0594.

Original languageEnglish
Pages (from-to)309-315
Number of pages7
JournalMain Group Chemistry
Volume1
Issue number3
DOIs
Publication statusPublished - 1 Jan 1996

ASJC Scopus subject areas

  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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