The structural chemistry of copper(II) hinokitiol and its adducts

M C Barret; M F Mahon; K C Molloy; P Wright; J E Creeth

doi:10.1016/s0277-5387(02)01064-1

The structural chemistry of copper(II) hinokitiol and its adducts

M C Barret
, M F Mahon
, K C Molloy
, P Wright
, J E Creeth

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

20 Citations (SciVal)

Abstract

The structure of copper(II) hinokitiol has been determined. Two modifications are possible, one containing only isolated, four-coordinate, square-planar complexes, while a second modification contains both monomers, along with eclipsed and staggered dimers generated through intermolecular O-->Cu interactions. Five-coordinate copper is also present in the adduct Cu(hino)(2). pyridine, whose structure has also been determined for comparison. (C) 2002 Elsevier Science Ltd. All rights reserved.

Original language	English
Pages (from-to)	1761-1766
Number of pages	6
Journal	Polyhedron
Volume	21
Issue number	17
DOIs	https://doi.org/10.1016/s0277-5387(02)01064-1
Publication status	Published - 2002

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ID number: ISI:000177222600012

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10.1016/s0277-5387(02)01064-1

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abstract = "The structure of copper(II) hinokitiol has been determined. Two modifications are possible, one containing only isolated, four-coordinate, square-planar complexes, while a second modification contains both monomers, along with eclipsed and staggered dimers generated through intermolecular O-->Cu interactions. Five-coordinate copper is also present in the adduct Cu(hino)(2). pyridine, whose structure has also been determined for comparison. (C) 2002 Elsevier Science Ltd. All rights reserved.",

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AU - Mahon, M F

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AU - Wright, P

AU - Creeth, J E

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AB - The structure of copper(II) hinokitiol has been determined. Two modifications are possible, one containing only isolated, four-coordinate, square-planar complexes, while a second modification contains both monomers, along with eclipsed and staggered dimers generated through intermolecular O-->Cu interactions. Five-coordinate copper is also present in the adduct Cu(hino)(2). pyridine, whose structure has also been determined for comparison. (C) 2002 Elsevier Science Ltd. All rights reserved.

U2 - 10.1016/s0277-5387(02)01064-1

DO - 10.1016/s0277-5387(02)01064-1

M3 - Article

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VL - 21

SP - 1761

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JO - Polyhedron

JF - Polyhedron

IS - 17

ER -

The structural chemistry of copper(II) hinokitiol and its adducts

Abstract

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