The structural chemistry of copper(II) hinokitiol and its adducts

M C Barret; M F Mahon; K C Molloy; P Wright; J E Creeth

The structural chemistry of copper(II) hinokitiol and its adducts

M C Barret, M F Mahon, K C Molloy, P Wright, J E Creeth

Department of Chemistry

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19 Citations (SciVal)

Abstract

The structure of copper(II) hinokitiol has been determined. Two modifications are possible, one containing only isolated, four-coordinate, square-planar complexes, while a second modification contains both monomers, along with eclipsed and staggered dimers generated through intermolecular O-->Cu interactions. Five-coordinate copper is also present in the adduct Cu(hino)(2). pyridine, whose structure has also been determined for comparison. (C) 2002 Elsevier Science Ltd. All rights reserved.

Original language	English
Pages (from-to)	1761-1766
Number of pages	6
Journal	Polyhedron
Volume	21
Issue number	17
Publication status	Published - 2002

Bibliographical note

ID number: ISI:000177222600012

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title = "The structural chemistry of copper(II) hinokitiol and its adducts",

abstract = "The structure of copper(II) hinokitiol has been determined. Two modifications are possible, one containing only isolated, four-coordinate, square-planar complexes, while a second modification contains both monomers, along with eclipsed and staggered dimers generated through intermolecular O-->Cu interactions. Five-coordinate copper is also present in the adduct Cu(hino)(2). pyridine, whose structure has also been determined for comparison. (C) 2002 Elsevier Science Ltd. All rights reserved.",

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T1 - The structural chemistry of copper(II) hinokitiol and its adducts

AU - Barret, M C

AU - Mahon, M F

AU - Molloy, K C

AU - Wright, P

AU - Creeth, J E

N1 - ID number: ISI:000177222600012

PY - 2002

Y1 - 2002

N2 - The structure of copper(II) hinokitiol has been determined. Two modifications are possible, one containing only isolated, four-coordinate, square-planar complexes, while a second modification contains both monomers, along with eclipsed and staggered dimers generated through intermolecular O-->Cu interactions. Five-coordinate copper is also present in the adduct Cu(hino)(2). pyridine, whose structure has also been determined for comparison. (C) 2002 Elsevier Science Ltd. All rights reserved.

AB - The structure of copper(II) hinokitiol has been determined. Two modifications are possible, one containing only isolated, four-coordinate, square-planar complexes, while a second modification contains both monomers, along with eclipsed and staggered dimers generated through intermolecular O-->Cu interactions. Five-coordinate copper is also present in the adduct Cu(hino)(2). pyridine, whose structure has also been determined for comparison. (C) 2002 Elsevier Science Ltd. All rights reserved.

M3 - Article

SN - 0277-5387

VL - 21

SP - 1761

EP - 1766

JO - Polyhedron

JF - Polyhedron

IS - 17

ER -

The structural chemistry of copper(II) hinokitiol and its adducts

Abstract

Bibliographical note

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