The structural chemistry of copper(II) hinokitiol and its adducts

M C Barret, M F Mahon, K C Molloy, P Wright, J E Creeth

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Abstract

The structure of copper(II) hinokitiol has been determined. Two modifications are possible, one containing only isolated, four-coordinate, square-planar complexes, while a second modification contains both monomers, along with eclipsed and staggered dimers generated through intermolecular O-->Cu interactions. Five-coordinate copper is also present in the adduct Cu(hino)(2). pyridine, whose structure has also been determined for comparison. (C) 2002 Elsevier Science Ltd. All rights reserved.
Original languageEnglish
Pages (from-to)1761-1766
Number of pages6
JournalPolyhedron
Volume21
Issue number17
Publication statusPublished - 2002

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    Barret, M. C., Mahon, M. F., Molloy, K. C., Wright, P., & Creeth, J. E. (2002). The structural chemistry of copper(II) hinokitiol and its adducts. Polyhedron, 21(17), 1761-1766.