The sergeants-and-soldiers effect: chiral amplification in naphthalenediimide nanotubes

Tom W. Anderson; Jeremy K. M. Sanders; G. Dan Pantos

doi:10.1039/c0ob00027b

The sergeants-and-soldiers effect: chiral amplification in naphthalenediimide nanotubes

Tom W. Anderson, Jeremy K. M. Sanders, G. Dan Pantos

University of Cambridge

Research output: Contribution to journal › Article › peer-review

55 Citations (SciVal)

Abstract

Self-assembling naphthalenediimide (NDI)-based helical organic nanotubes display sergeants-and-soldiers behaviour, chiral monomers imposing a supramolecular structure upon achiral monomers. Several achiral NDI monomers were synthesised and their ability to incorporate into supramolecular nanotubes was studied. Nanotubes containing predominantly the most effective soldier, derived from 1-aminocyclopropane-carboxylic acid, are effective hosts for C(60).

Original language	English
Pages (from-to)	4274-4280
Number of pages	7
Journal	Organic and Biomolecular Chemistry
Volume	8
Issue number	19
DOIs	https://doi.org/10.1039/c0ob00027b
Publication status	Published - 7 Oct 2010

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abstract = "Self-assembling naphthalenediimide (NDI)-based helical organic nanotubes display sergeants-and-soldiers behaviour, chiral monomers imposing a supramolecular structure upon achiral monomers. Several achiral NDI monomers were synthesised and their ability to incorporate into supramolecular nanotubes was studied. Nanotubes containing predominantly the most effective soldier, derived from 1-aminocyclopropane-carboxylic acid, are effective hosts for C(60).",

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AB - Self-assembling naphthalenediimide (NDI)-based helical organic nanotubes display sergeants-and-soldiers behaviour, chiral monomers imposing a supramolecular structure upon achiral monomers. Several achiral NDI monomers were synthesised and their ability to incorporate into supramolecular nanotubes was studied. Nanotubes containing predominantly the most effective soldier, derived from 1-aminocyclopropane-carboxylic acid, are effective hosts for C(60).

U2 - 10.1039/c0ob00027b

DO - 10.1039/c0ob00027b

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JO - Organic and Biomolecular Chemistry

JF - Organic and Biomolecular Chemistry

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The sergeants-and-soldiers effect: chiral amplification in naphthalenediimide nanotubes

Abstract

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